1-tert-Butyl 2-ethyl 5-bromo-3-(thio­phen-2-ylcarbon­yl)-1H-indole-1,2-dicarboxyl­ate

In the title compound, C(21)H(20)BrNO(5)S, the thio­phene group is located above the mean plane of the indole ring and displays rotational disorder (i.e. rotation through 180°). The site occupancy of the major component is 0.902 (2), while that of the minor component is 0.098 (2). In the crystal, pa...

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Detalles Bibliográficos
Autores principales: Hassam, Mohammad, Smith, Vincent J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569770/
https://www.ncbi.nlm.nih.gov/pubmed/23424516
http://dx.doi.org/10.1107/S1600536813000809
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author Hassam, Mohammad
Smith, Vincent J.
author_facet Hassam, Mohammad
Smith, Vincent J.
author_sort Hassam, Mohammad
collection PubMed
description In the title compound, C(21)H(20)BrNO(5)S, the thio­phene group is located above the mean plane of the indole ring and displays rotational disorder (i.e. rotation through 180°). The site occupancy of the major component is 0.902 (2), while that of the minor component is 0.098 (2). In the crystal, pairs of weak C—H⋯O inter­actions link the mol­ecules into centrosymmetric dimers.
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spelling pubmed-35697702013-02-19 1-tert-Butyl 2-ethyl 5-bromo-3-(thio­phen-2-ylcarbon­yl)-1H-indole-1,2-dicarboxyl­ate Hassam, Mohammad Smith, Vincent J. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(21)H(20)BrNO(5)S, the thio­phene group is located above the mean plane of the indole ring and displays rotational disorder (i.e. rotation through 180°). The site occupancy of the major component is 0.902 (2), while that of the minor component is 0.098 (2). In the crystal, pairs of weak C—H⋯O inter­actions link the mol­ecules into centrosymmetric dimers. International Union of Crystallography 2013-01-16 /pmc/articles/PMC3569770/ /pubmed/23424516 http://dx.doi.org/10.1107/S1600536813000809 Text en © Hassam and Smith 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Hassam, Mohammad
Smith, Vincent J.
1-tert-Butyl 2-ethyl 5-bromo-3-(thio­phen-2-ylcarbon­yl)-1H-indole-1,2-dicarboxyl­ate
title 1-tert-Butyl 2-ethyl 5-bromo-3-(thio­phen-2-ylcarbon­yl)-1H-indole-1,2-dicarboxyl­ate
title_full 1-tert-Butyl 2-ethyl 5-bromo-3-(thio­phen-2-ylcarbon­yl)-1H-indole-1,2-dicarboxyl­ate
title_fullStr 1-tert-Butyl 2-ethyl 5-bromo-3-(thio­phen-2-ylcarbon­yl)-1H-indole-1,2-dicarboxyl­ate
title_full_unstemmed 1-tert-Butyl 2-ethyl 5-bromo-3-(thio­phen-2-ylcarbon­yl)-1H-indole-1,2-dicarboxyl­ate
title_short 1-tert-Butyl 2-ethyl 5-bromo-3-(thio­phen-2-ylcarbon­yl)-1H-indole-1,2-dicarboxyl­ate
title_sort 1-tert-butyl 2-ethyl 5-bromo-3-(thio­phen-2-ylcarbon­yl)-1h-indole-1,2-dicarboxyl­ate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569770/
https://www.ncbi.nlm.nih.gov/pubmed/23424516
http://dx.doi.org/10.1107/S1600536813000809
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