3-Chloro-4-fluoro­anilinium picrate

In the title picrate salt of a dihalogenated aniline derivative, C(6)H(6)ClF(+)·C(6)H(2)N(3)O(7) (−), the intra­cyclic C—C—C angles in the picrate anion cover a broad range [111.95 (12)–125.38 (13)°], while those in the aromatic cation span a much narrower range [118.25 (14)–122.33 (13)°]. In the cr...

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Autores principales: Sarojini, Balladka K., Narayana, Badiadka, Yathirajan, Hemmige S., Gerber, Thomas, van Brecht, Benjamin, Betz, Richard
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569773/
https://www.ncbi.nlm.nih.gov/pubmed/23424519
http://dx.doi.org/10.1107/S1600536813000718
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author Sarojini, Balladka K.
Narayana, Badiadka
Yathirajan, Hemmige S.
Gerber, Thomas
van Brecht, Benjamin
Betz, Richard
author_facet Sarojini, Balladka K.
Narayana, Badiadka
Yathirajan, Hemmige S.
Gerber, Thomas
van Brecht, Benjamin
Betz, Richard
author_sort Sarojini, Balladka K.
collection PubMed
description In the title picrate salt of a dihalogenated aniline derivative, C(6)H(6)ClF(+)·C(6)H(2)N(3)O(7) (−), the intra­cyclic C—C—C angles in the picrate anion cover a broad range [111.95 (12)–125.38 (13)°], while those in the aromatic cation span a much narrower range [118.25 (14)–122.33 (13)°]. In the crystal, classical N—H⋯O hydrogen bonds, as well as C—H⋯O contacts, connect the ions into layers parallel to (001).
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spelling pubmed-35697732013-02-19 3-Chloro-4-fluoro­anilinium picrate Sarojini, Balladka K. Narayana, Badiadka Yathirajan, Hemmige S. Gerber, Thomas van Brecht, Benjamin Betz, Richard Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title picrate salt of a dihalogenated aniline derivative, C(6)H(6)ClF(+)·C(6)H(2)N(3)O(7) (−), the intra­cyclic C—C—C angles in the picrate anion cover a broad range [111.95 (12)–125.38 (13)°], while those in the aromatic cation span a much narrower range [118.25 (14)–122.33 (13)°]. In the crystal, classical N—H⋯O hydrogen bonds, as well as C—H⋯O contacts, connect the ions into layers parallel to (001). International Union of Crystallography 2013-01-16 /pmc/articles/PMC3569773/ /pubmed/23424519 http://dx.doi.org/10.1107/S1600536813000718 Text en © Sarojini et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Sarojini, Balladka K.
Narayana, Badiadka
Yathirajan, Hemmige S.
Gerber, Thomas
van Brecht, Benjamin
Betz, Richard
3-Chloro-4-fluoro­anilinium picrate
title 3-Chloro-4-fluoro­anilinium picrate
title_full 3-Chloro-4-fluoro­anilinium picrate
title_fullStr 3-Chloro-4-fluoro­anilinium picrate
title_full_unstemmed 3-Chloro-4-fluoro­anilinium picrate
title_short 3-Chloro-4-fluoro­anilinium picrate
title_sort 3-chloro-4-fluoro­anilinium picrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569773/
https://www.ncbi.nlm.nih.gov/pubmed/23424519
http://dx.doi.org/10.1107/S1600536813000718
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AT gerberthomas 3chloro4fluoroaniliniumpicrate
AT vanbrechtbenjamin 3chloro4fluoroaniliniumpicrate
AT betzrichard 3chloro4fluoroaniliniumpicrate

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