3-[2-(Triphenyl­phosphanyl­idene)acet­yl]-2H-chromen-2-one

In the title compound, C(29)H(21)O(3)P, a coumarin-substitued ylid, the P atom is linked to three benzene rings and a planar coumarin moiety via a methyl­enecarbonyl group. The bond lengths in the P=C–C=O fragment clearly indicate a delocalized system involving the olefinic and carbonyl bonds. The m...

Descripción completa

Detalles Bibliográficos
Autores principales: Taha, Muhammad, Ismail, Nor Hadiani, Aziza, Ahmad Nazif, Shah, Syed Adnan Ali, Yousuf, Sammer
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569778/
https://www.ncbi.nlm.nih.gov/pubmed/23424524
http://dx.doi.org/10.1107/S160053681300127X
_version_ 1782258960523329536
author Taha, Muhammad
Ismail, Nor Hadiani
Aziza, Ahmad Nazif
Shah, Syed Adnan Ali
Yousuf, Sammer
author_facet Taha, Muhammad
Ismail, Nor Hadiani
Aziza, Ahmad Nazif
Shah, Syed Adnan Ali
Yousuf, Sammer
author_sort Taha, Muhammad
collection PubMed
description In the title compound, C(29)H(21)O(3)P, a coumarin-substitued ylid, the P atom is linked to three benzene rings and a planar coumarin moiety via a methyl­enecarbonyl group. The bond lengths in the P=C–C=O fragment clearly indicate a delocalized system involving the olefinic and carbonyl bonds. The mol­ecular structure is stabilized by an intra­molecular C—H⋯O inter­action that results in an S7 graph-set ring motif. In the crystal, mol­ecules are linked into a three-dimensional framework by C—H⋯O hydrogen bonds.
format Online
Article
Text
id pubmed-3569778
institution National Center for Biotechnology Information
language English
publishDate 2013
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-35697782013-02-19 3-[2-(Triphenyl­phosphanyl­idene)acet­yl]-2H-chromen-2-one Taha, Muhammad Ismail, Nor Hadiani Aziza, Ahmad Nazif Shah, Syed Adnan Ali Yousuf, Sammer Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(29)H(21)O(3)P, a coumarin-substitued ylid, the P atom is linked to three benzene rings and a planar coumarin moiety via a methyl­enecarbonyl group. The bond lengths in the P=C–C=O fragment clearly indicate a delocalized system involving the olefinic and carbonyl bonds. The mol­ecular structure is stabilized by an intra­molecular C—H⋯O inter­action that results in an S7 graph-set ring motif. In the crystal, mol­ecules are linked into a three-dimensional framework by C—H⋯O hydrogen bonds. International Union of Crystallography 2013-01-19 /pmc/articles/PMC3569778/ /pubmed/23424524 http://dx.doi.org/10.1107/S160053681300127X Text en © Taha et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Taha, Muhammad
Ismail, Nor Hadiani
Aziza, Ahmad Nazif
Shah, Syed Adnan Ali
Yousuf, Sammer
3-[2-(Triphenyl­phosphanyl­idene)acet­yl]-2H-chromen-2-one
title 3-[2-(Triphenyl­phosphanyl­idene)acet­yl]-2H-chromen-2-one
title_full 3-[2-(Triphenyl­phosphanyl­idene)acet­yl]-2H-chromen-2-one
title_fullStr 3-[2-(Triphenyl­phosphanyl­idene)acet­yl]-2H-chromen-2-one
title_full_unstemmed 3-[2-(Triphenyl­phosphanyl­idene)acet­yl]-2H-chromen-2-one
title_short 3-[2-(Triphenyl­phosphanyl­idene)acet­yl]-2H-chromen-2-one
title_sort 3-[2-(triphenyl­phosphanyl­idene)acet­yl]-2h-chromen-2-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569778/
https://www.ncbi.nlm.nih.gov/pubmed/23424524
http://dx.doi.org/10.1107/S160053681300127X
work_keys_str_mv AT tahamuhammad 32triphenylphosphanylideneacetyl2hchromen2one
AT ismailnorhadiani 32triphenylphosphanylideneacetyl2hchromen2one
AT azizaahmadnazif 32triphenylphosphanylideneacetyl2hchromen2one
AT shahsyedadnanali 32triphenylphosphanylideneacetyl2hchromen2one
AT yousufsammer 32triphenylphosphanylideneacetyl2hchromen2one

Ejemplares similares