3′′-(2-Fluoro­benzyl­idene)-4′-(2-fluoro­phen­yl)-1′-methyl­dispiro­[acenaphthyl­ene-1,2′-pyrrolidine-3′,1′′-cyclo­penta­ne]-2,2′′-dione

In the title compound, C(33)H(25)F(2)NO(2), the acenaphthene ring system forms dihedral angles of 50.93 (14) and 36.89 (14)° with the benzene rings. The pyrrolidine and cyclo­penta­none rings adopt envelope (with the N atom as the flap) and twisted conformations, respectively. In the crystal, C—H⋯O...

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Detalles Bibliográficos
Autores principales: Chen, Gao-Zhi, Wei, Xiao-Yan, Wang, Yi, Ren, Lu-Qing, Li, Xiao-Kun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569782/
https://www.ncbi.nlm.nih.gov/pubmed/23424528
http://dx.doi.org/10.1107/S1600536812051550
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author Chen, Gao-Zhi
Wei, Xiao-Yan
Wang, Yi
Ren, Lu-Qing
Li, Xiao-Kun
author_facet Chen, Gao-Zhi
Wei, Xiao-Yan
Wang, Yi
Ren, Lu-Qing
Li, Xiao-Kun
author_sort Chen, Gao-Zhi
collection PubMed
description In the title compound, C(33)H(25)F(2)NO(2), the acenaphthene ring system forms dihedral angles of 50.93 (14) and 36.89 (14)° with the benzene rings. The pyrrolidine and cyclo­penta­none rings adopt envelope (with the N atom as the flap) and twisted conformations, respectively. In the crystal, C—H⋯O and C—H⋯F inter­actions link the mol­ecules.
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spelling pubmed-35697822013-02-19 3′′-(2-Fluoro­benzyl­idene)-4′-(2-fluoro­phen­yl)-1′-methyl­dispiro­[acenaphthyl­ene-1,2′-pyrrolidine-3′,1′′-cyclo­penta­ne]-2,2′′-dione Chen, Gao-Zhi Wei, Xiao-Yan Wang, Yi Ren, Lu-Qing Li, Xiao-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(33)H(25)F(2)NO(2), the acenaphthene ring system forms dihedral angles of 50.93 (14) and 36.89 (14)° with the benzene rings. The pyrrolidine and cyclo­penta­none rings adopt envelope (with the N atom as the flap) and twisted conformations, respectively. In the crystal, C—H⋯O and C—H⋯F inter­actions link the mol­ecules. International Union of Crystallography 2013-01-19 /pmc/articles/PMC3569782/ /pubmed/23424528 http://dx.doi.org/10.1107/S1600536812051550 Text en © Chen et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Chen, Gao-Zhi
Wei, Xiao-Yan
Wang, Yi
Ren, Lu-Qing
Li, Xiao-Kun
3′′-(2-Fluoro­benzyl­idene)-4′-(2-fluoro­phen­yl)-1′-methyl­dispiro­[acenaphthyl­ene-1,2′-pyrrolidine-3′,1′′-cyclo­penta­ne]-2,2′′-dione
title 3′′-(2-Fluoro­benzyl­idene)-4′-(2-fluoro­phen­yl)-1′-methyl­dispiro­[acenaphthyl­ene-1,2′-pyrrolidine-3′,1′′-cyclo­penta­ne]-2,2′′-dione
title_full 3′′-(2-Fluoro­benzyl­idene)-4′-(2-fluoro­phen­yl)-1′-methyl­dispiro­[acenaphthyl­ene-1,2′-pyrrolidine-3′,1′′-cyclo­penta­ne]-2,2′′-dione
title_fullStr 3′′-(2-Fluoro­benzyl­idene)-4′-(2-fluoro­phen­yl)-1′-methyl­dispiro­[acenaphthyl­ene-1,2′-pyrrolidine-3′,1′′-cyclo­penta­ne]-2,2′′-dione
title_full_unstemmed 3′′-(2-Fluoro­benzyl­idene)-4′-(2-fluoro­phen­yl)-1′-methyl­dispiro­[acenaphthyl­ene-1,2′-pyrrolidine-3′,1′′-cyclo­penta­ne]-2,2′′-dione
title_short 3′′-(2-Fluoro­benzyl­idene)-4′-(2-fluoro­phen­yl)-1′-methyl­dispiro­[acenaphthyl­ene-1,2′-pyrrolidine-3′,1′′-cyclo­penta­ne]-2,2′′-dione
title_sort 3′′-(2-fluoro­benzyl­idene)-4′-(2-fluoro­phen­yl)-1′-methyl­dispiro­[acenaphthyl­ene-1,2′-pyrrolidine-3′,1′′-cyclo­penta­ne]-2,2′′-dione
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569782/
https://www.ncbi.nlm.nih.gov/pubmed/23424528
http://dx.doi.org/10.1107/S1600536812051550
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