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2-Chloro-8,8-dimethyl-8,9-dihydro-7H-chromeno[2,3-b]quinoline-10,12-dione

The asymmetric unit of the title compound, C(18)H(14)ClNO(3), contains two independent mol­ecules (A and B). In both mol­ecules, the cyclo­hexa­none ring has a chair conformation. The dihedral angles between the pyran ring and the pyridine and chloro­phenyl rings are 2.13 (9) and 2.19 (9)°, respecti...

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Autores principales: Srinivasan, Thothadri, Yuvaraj, Panneerselvam, Reddy, Boreddy S. R., Velmurugan, Devadasan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569785/
https://www.ncbi.nlm.nih.gov/pubmed/23424531
http://dx.doi.org/10.1107/S1600536813001062
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author Srinivasan, Thothadri
Yuvaraj, Panneerselvam
Reddy, Boreddy S. R.
Velmurugan, Devadasan
author_facet Srinivasan, Thothadri
Yuvaraj, Panneerselvam
Reddy, Boreddy S. R.
Velmurugan, Devadasan
author_sort Srinivasan, Thothadri
collection PubMed
description The asymmetric unit of the title compound, C(18)H(14)ClNO(3), contains two independent mol­ecules (A and B). In both mol­ecules, the cyclo­hexa­none ring has a chair conformation. The dihedral angles between the pyran ring and the pyridine and chloro­phenyl rings are 2.13 (9) and 2.19 (9)°, respectively, in A, and 0.82 (9) and 1.93 (9)°, respectively, in B. The carbonyl O atoms deviate from the pyran and benzene rings to which they are attached by −0.092 (2) and 0.064 (2) Å, respectively, in A, and by −0.080 (2) and −0.063 (2) Å, respectively, in B. In the crystal, the A mol­ecules are linked via C—H⋯O hydrogen bonds, forming double-stranded chains along [100]. They lie parallel to the double-stranded chains formed by the B mol­ecules, which are also linked via C—H⋯O hydrogen bonds. The chains stack up the c axis in an –A–A–B–B–A–A– manner, with a number of π–π inter­actions involving A and B mol­ecules; the centroid–centroid distances vary from 3.4862 (11) to 3.6848 (11) Å
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spelling pubmed-35697852013-02-19 2-Chloro-8,8-dimethyl-8,9-dihydro-7H-chromeno[2,3-b]quinoline-10,12-dione Srinivasan, Thothadri Yuvaraj, Panneerselvam Reddy, Boreddy S. R. Velmurugan, Devadasan Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(18)H(14)ClNO(3), contains two independent mol­ecules (A and B). In both mol­ecules, the cyclo­hexa­none ring has a chair conformation. The dihedral angles between the pyran ring and the pyridine and chloro­phenyl rings are 2.13 (9) and 2.19 (9)°, respectively, in A, and 0.82 (9) and 1.93 (9)°, respectively, in B. The carbonyl O atoms deviate from the pyran and benzene rings to which they are attached by −0.092 (2) and 0.064 (2) Å, respectively, in A, and by −0.080 (2) and −0.063 (2) Å, respectively, in B. In the crystal, the A mol­ecules are linked via C—H⋯O hydrogen bonds, forming double-stranded chains along [100]. They lie parallel to the double-stranded chains formed by the B mol­ecules, which are also linked via C—H⋯O hydrogen bonds. The chains stack up the c axis in an –A–A–B–B–A–A– manner, with a number of π–π inter­actions involving A and B mol­ecules; the centroid–centroid distances vary from 3.4862 (11) to 3.6848 (11) Å International Union of Crystallography 2013-01-19 /pmc/articles/PMC3569785/ /pubmed/23424531 http://dx.doi.org/10.1107/S1600536813001062 Text en © Srinivasan et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Srinivasan, Thothadri
Yuvaraj, Panneerselvam
Reddy, Boreddy S. R.
Velmurugan, Devadasan
2-Chloro-8,8-dimethyl-8,9-dihydro-7H-chromeno[2,3-b]quinoline-10,12-dione
title 2-Chloro-8,8-dimethyl-8,9-dihydro-7H-chromeno[2,3-b]quinoline-10,12-dione
title_full 2-Chloro-8,8-dimethyl-8,9-dihydro-7H-chromeno[2,3-b]quinoline-10,12-dione
title_fullStr 2-Chloro-8,8-dimethyl-8,9-dihydro-7H-chromeno[2,3-b]quinoline-10,12-dione
title_full_unstemmed 2-Chloro-8,8-dimethyl-8,9-dihydro-7H-chromeno[2,3-b]quinoline-10,12-dione
title_short 2-Chloro-8,8-dimethyl-8,9-dihydro-7H-chromeno[2,3-b]quinoline-10,12-dione
title_sort 2-chloro-8,8-dimethyl-8,9-dihydro-7h-chromeno[2,3-b]quinoline-10,12-dione
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569785/
https://www.ncbi.nlm.nih.gov/pubmed/23424531
http://dx.doi.org/10.1107/S1600536813001062
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