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5,11-Dimethyl-6,12-dimeth­oxy­indolo[3,2-b]carbazole

The title compound, C(22)H(20)N(2)O(2), was prepared in a twofold Cadogan cyclization followed by double N-methyl­ation. The crystal structure is characterized by a zigzag arrangement of centrosymmetric mol­ecules. The indolocarbazole framework is essentially planar [maximum deviation = 0.028 (2) Å]...

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Detalles Bibliográficos
Autores principales: Wrobel, Norma, Witulski, Bernhard, Schollmeyer, Dieter, Detert, Heiner
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569787/
https://www.ncbi.nlm.nih.gov/pubmed/23424533
http://dx.doi.org/10.1107/S1600536813001463
Descripción
Sumario:The title compound, C(22)H(20)N(2)O(2), was prepared in a twofold Cadogan cyclization followed by double N-methyl­ation. The crystal structure is characterized by a zigzag arrangement of centrosymmetric mol­ecules. The indolocarbazole framework is essentially planar [maximum deviation = 0.028 (2) Å] and the meth­oxy groups are orthogonal to this plane [C—C—O—C torsion angle = −88.2 (2)°]. The lengths of the C—N bonds are nearly identical and all C—C bonds of the pyrrole subunit are significantly longer than the C—C bonds in the benzene rings.