2-[4-(Trifluoro­meth­oxy)phen­yl]-1H-benzimidazole

In the title compound, C(14)H(9)F(3)N(2)O, the best planes of the benzimidazole group and benzene ring form a dihedral angle of 26.68 (3)°. In the crystal, N—H⋯N hydrogen bonds link the mol­ecules into infinite chains parallel to the c axis. Stacking inter­actions between the benzimidazole groups [c...

Descripción completa

Detalles Bibliográficos
Autores principales: Fathima, Nikhath, Krishnamurthy, M. S., Begum, Noor Shahina
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569794/
https://www.ncbi.nlm.nih.gov/pubmed/23424540
http://dx.doi.org/10.1107/S1600536813001220
_version_ 1782258964275134464
author Fathima, Nikhath
Krishnamurthy, M. S.
Begum, Noor Shahina
author_facet Fathima, Nikhath
Krishnamurthy, M. S.
Begum, Noor Shahina
author_sort Fathima, Nikhath
collection PubMed
description In the title compound, C(14)H(9)F(3)N(2)O, the best planes of the benzimidazole group and benzene ring form a dihedral angle of 26.68 (3)°. In the crystal, N—H⋯N hydrogen bonds link the mol­ecules into infinite chains parallel to the c axis. Stacking inter­actions between the benzimidazole groups [centroid–centroid distance = 3.594 (5) Å] assemble the mol­ecules into layers parallel to (100). The trifluoro­methyl group is disordered over three sets of sites with site-occupancy factors of 0.787 (4), 0.107 (7) and 0.106 (7).
format Online
Article
Text
id pubmed-3569794
institution National Center for Biotechnology Information
language English
publishDate 2013
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-35697942013-02-19 2-[4-(Trifluoro­meth­oxy)phen­yl]-1H-benzimidazole Fathima, Nikhath Krishnamurthy, M. S. Begum, Noor Shahina Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(14)H(9)F(3)N(2)O, the best planes of the benzimidazole group and benzene ring form a dihedral angle of 26.68 (3)°. In the crystal, N—H⋯N hydrogen bonds link the mol­ecules into infinite chains parallel to the c axis. Stacking inter­actions between the benzimidazole groups [centroid–centroid distance = 3.594 (5) Å] assemble the mol­ecules into layers parallel to (100). The trifluoro­methyl group is disordered over three sets of sites with site-occupancy factors of 0.787 (4), 0.107 (7) and 0.106 (7). International Union of Crystallography 2013-01-19 /pmc/articles/PMC3569794/ /pubmed/23424540 http://dx.doi.org/10.1107/S1600536813001220 Text en © Fathima et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Fathima, Nikhath
Krishnamurthy, M. S.
Begum, Noor Shahina
2-[4-(Trifluoro­meth­oxy)phen­yl]-1H-benzimidazole
title 2-[4-(Trifluoro­meth­oxy)phen­yl]-1H-benzimidazole
title_full 2-[4-(Trifluoro­meth­oxy)phen­yl]-1H-benzimidazole
title_fullStr 2-[4-(Trifluoro­meth­oxy)phen­yl]-1H-benzimidazole
title_full_unstemmed 2-[4-(Trifluoro­meth­oxy)phen­yl]-1H-benzimidazole
title_short 2-[4-(Trifluoro­meth­oxy)phen­yl]-1H-benzimidazole
title_sort 2-[4-(trifluoro­meth­oxy)phen­yl]-1h-benzimidazole
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569794/
https://www.ncbi.nlm.nih.gov/pubmed/23424540
http://dx.doi.org/10.1107/S1600536813001220
work_keys_str_mv AT fathimanikhath 24trifluoromethoxyphenyl1hbenzimidazole
AT krishnamurthyms 24trifluoromethoxyphenyl1hbenzimidazole
AT begumnoorshahina 24trifluoromethoxyphenyl1hbenzimidazole

Ejemplares similares