(6R*,10R*)-Dimethyl 1,4-dioxaspiro­[4.5]decane-6,10-dicarboxyl­ate

The title compound, C(12)H(18)O(6), is in the usual chair conformation with the two ester functions in a 1,3-trans orientation. With a value of 1.439 (2) Å, the pseudo-axial C—O bond of the 1,3-dioxolane ring is slightly longer than the corresponding equatorial C—O bond of 1.424 (3) Å. The O—C—O ang...

Descripción completa

Detalles Bibliográficos
Autores principales: Jahangiri, Amita, Wendt, Ola F., Strand, Daniel
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569795/
https://www.ncbi.nlm.nih.gov/pubmed/23424541
http://dx.doi.org/10.1107/S160053681300161X
Descripción
Sumario:The title compound, C(12)H(18)O(6), is in the usual chair conformation with the two ester functions in a 1,3-trans orientation. With a value of 1.439 (2) Å, the pseudo-axial C—O bond of the 1,3-dioxolane ring is slightly longer than the corresponding equatorial C—O bond of 1.424 (3) Å. The O—C—O angle of the dioxolane ring is 106.25 (17)°.

Ejemplares similares