(6R*,10R*)-Dimethyl 1,4-dioxaspiro­[4.5]decane-6,10-dicarboxyl­ate

The title compound, C(12)H(18)O(6), is in the usual chair conformation with the two ester functions in a 1,3-trans orientation. With a value of 1.439 (2) Å, the pseudo-axial C—O bond of the 1,3-dioxolane ring is slightly longer than the corresponding equatorial C—O bond of 1.424 (3) Å. The O—C—O ang...

Descripción completa

Detalles Bibliográficos
Autores principales: Jahangiri, Amita, Wendt, Ola F., Strand, Daniel
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569795/
https://www.ncbi.nlm.nih.gov/pubmed/23424541
http://dx.doi.org/10.1107/S160053681300161X
_version_ 1782258964518404096
author Jahangiri, Amita
Wendt, Ola F.
Strand, Daniel
author_facet Jahangiri, Amita
Wendt, Ola F.
Strand, Daniel
author_sort Jahangiri, Amita
collection PubMed
description The title compound, C(12)H(18)O(6), is in the usual chair conformation with the two ester functions in a 1,3-trans orientation. With a value of 1.439 (2) Å, the pseudo-axial C—O bond of the 1,3-dioxolane ring is slightly longer than the corresponding equatorial C—O bond of 1.424 (3) Å. The O—C—O angle of the dioxolane ring is 106.25 (17)°.
format Online
Article
Text
id pubmed-3569795
institution National Center for Biotechnology Information
language English
publishDate 2013
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-35697952013-02-19 (6R*,10R*)-Dimethyl 1,4-dioxaspiro­[4.5]decane-6,10-dicarboxyl­ate Jahangiri, Amita Wendt, Ola F. Strand, Daniel Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(12)H(18)O(6), is in the usual chair conformation with the two ester functions in a 1,3-trans orientation. With a value of 1.439 (2) Å, the pseudo-axial C—O bond of the 1,3-dioxolane ring is slightly longer than the corresponding equatorial C—O bond of 1.424 (3) Å. The O—C—O angle of the dioxolane ring is 106.25 (17)°. International Union of Crystallography 2013-01-19 /pmc/articles/PMC3569795/ /pubmed/23424541 http://dx.doi.org/10.1107/S160053681300161X Text en © Jahangiri et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Jahangiri, Amita
Wendt, Ola F.
Strand, Daniel
(6R*,10R*)-Dimethyl 1,4-dioxaspiro­[4.5]decane-6,10-dicarboxyl­ate
title (6R*,10R*)-Dimethyl 1,4-dioxaspiro­[4.5]decane-6,10-dicarboxyl­ate
title_full (6R*,10R*)-Dimethyl 1,4-dioxaspiro­[4.5]decane-6,10-dicarboxyl­ate
title_fullStr (6R*,10R*)-Dimethyl 1,4-dioxaspiro­[4.5]decane-6,10-dicarboxyl­ate
title_full_unstemmed (6R*,10R*)-Dimethyl 1,4-dioxaspiro­[4.5]decane-6,10-dicarboxyl­ate
title_short (6R*,10R*)-Dimethyl 1,4-dioxaspiro­[4.5]decane-6,10-dicarboxyl­ate
title_sort (6r*,10r*)-dimethyl 1,4-dioxaspiro­[4.5]decane-6,10-dicarboxyl­ate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569795/
https://www.ncbi.nlm.nih.gov/pubmed/23424541
http://dx.doi.org/10.1107/S160053681300161X
work_keys_str_mv AT jahangiriamita 6r10rdimethyl14dioxaspiro45decane610dicarboxylate
AT wendtolaf 6r10rdimethyl14dioxaspiro45decane610dicarboxylate
AT stranddaniel 6r10rdimethyl14dioxaspiro45decane610dicarboxylate

Ejemplares similares