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14-Ethoxy-4,6,9-trimethyl-8,12-dioxa-4,6-diazatetracyclo[8.8.0.0(2,7).0(13,18)]octadeca-2(7),13,15,17-tetraene-3,5,11-trione
In the title compound, C(19)H(20)N(2)O(6), the pyrone and pyran rings adopt envelope conformations with the same common C atom as the flap, the dihedral angle between the planes of the remaining ring atoms being 68.27 (4)°. The planar atoms of the pyran ring and the diazacyclic ring are almost copl...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569800/ https://www.ncbi.nlm.nih.gov/pubmed/23424546 http://dx.doi.org/10.1107/S1600536813000743 |
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author | Jagadeesan, G. Kannan, D. Bakthadoss, M. Aravindhan, S. |
author_facet | Jagadeesan, G. Kannan, D. Bakthadoss, M. Aravindhan, S. |
author_sort | Jagadeesan, G. |
collection | PubMed |
description | In the title compound, C(19)H(20)N(2)O(6), the pyrone and pyran rings adopt envelope conformations with the same common C atom as the flap, the dihedral angle between the planes of the remaining ring atoms being 68.27 (4)°. The planar atoms of the pyran ring and the diazacyclic ring are almost coplanar, the dihedral angle between their mean planes being 3.29 (7)°. Moreover, the planar atoms of the pyrone ring and benzene ring of the coumarin unit are also close to coplanar, the dihedral angle between their mean planes being 8.03 (9)°. The methoxy group lies in the plane of the benzene ring, with a dihedral angle between their mean planes of 9.4 (2)°. In the crystal, the molecules are linked by C—H⋯O hydrogen bonds resulting in sheets of molecules in the ac plane. |
format | Online Article Text |
id | pubmed-3569800 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-35698002013-02-19 14-Ethoxy-4,6,9-trimethyl-8,12-dioxa-4,6-diazatetracyclo[8.8.0.0(2,7).0(13,18)]octadeca-2(7),13,15,17-tetraene-3,5,11-trione Jagadeesan, G. Kannan, D. Bakthadoss, M. Aravindhan, S. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(19)H(20)N(2)O(6), the pyrone and pyran rings adopt envelope conformations with the same common C atom as the flap, the dihedral angle between the planes of the remaining ring atoms being 68.27 (4)°. The planar atoms of the pyran ring and the diazacyclic ring are almost coplanar, the dihedral angle between their mean planes being 3.29 (7)°. Moreover, the planar atoms of the pyrone ring and benzene ring of the coumarin unit are also close to coplanar, the dihedral angle between their mean planes being 8.03 (9)°. The methoxy group lies in the plane of the benzene ring, with a dihedral angle between their mean planes of 9.4 (2)°. In the crystal, the molecules are linked by C—H⋯O hydrogen bonds resulting in sheets of molecules in the ac plane. International Union of Crystallography 2013-01-23 /pmc/articles/PMC3569800/ /pubmed/23424546 http://dx.doi.org/10.1107/S1600536813000743 Text en © Jagadeesan et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Jagadeesan, G. Kannan, D. Bakthadoss, M. Aravindhan, S. 14-Ethoxy-4,6,9-trimethyl-8,12-dioxa-4,6-diazatetracyclo[8.8.0.0(2,7).0(13,18)]octadeca-2(7),13,15,17-tetraene-3,5,11-trione |
title | 14-Ethoxy-4,6,9-trimethyl-8,12-dioxa-4,6-diazatetracyclo[8.8.0.0(2,7).0(13,18)]octadeca-2(7),13,15,17-tetraene-3,5,11-trione |
title_full | 14-Ethoxy-4,6,9-trimethyl-8,12-dioxa-4,6-diazatetracyclo[8.8.0.0(2,7).0(13,18)]octadeca-2(7),13,15,17-tetraene-3,5,11-trione |
title_fullStr | 14-Ethoxy-4,6,9-trimethyl-8,12-dioxa-4,6-diazatetracyclo[8.8.0.0(2,7).0(13,18)]octadeca-2(7),13,15,17-tetraene-3,5,11-trione |
title_full_unstemmed | 14-Ethoxy-4,6,9-trimethyl-8,12-dioxa-4,6-diazatetracyclo[8.8.0.0(2,7).0(13,18)]octadeca-2(7),13,15,17-tetraene-3,5,11-trione |
title_short | 14-Ethoxy-4,6,9-trimethyl-8,12-dioxa-4,6-diazatetracyclo[8.8.0.0(2,7).0(13,18)]octadeca-2(7),13,15,17-tetraene-3,5,11-trione |
title_sort | 14-ethoxy-4,6,9-trimethyl-8,12-dioxa-4,6-diazatetracyclo[8.8.0.0(2,7).0(13,18)]octadeca-2(7),13,15,17-tetraene-3,5,11-trione |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569800/ https://www.ncbi.nlm.nih.gov/pubmed/23424546 http://dx.doi.org/10.1107/S1600536813000743 |
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