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14-Eth­oxy-4,6,9-trimethyl-8,12-dioxa-4,6-diaza­tetra­cyclo­[8.8.0.0(2,7).0(13,18)]octa­deca-2(7),13,15,17-tetra­ene-3,5,11-trione

In the title compound, C(19)H(20)N(2)O(6), the pyrone and pyran rings adopt envelope conformations with the same common C atom as the flap, the dihedral angle between the planes of the remaining ring atoms being 68.27 (4)°. The planar atoms of the pyran ring and the diaza­cyclic ring are almost copl...

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Autores principales: Jagadeesan, G., Kannan, D., Bakthadoss, M., Aravindhan, S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569800/
https://www.ncbi.nlm.nih.gov/pubmed/23424546
http://dx.doi.org/10.1107/S1600536813000743
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author Jagadeesan, G.
Kannan, D.
Bakthadoss, M.
Aravindhan, S.
author_facet Jagadeesan, G.
Kannan, D.
Bakthadoss, M.
Aravindhan, S.
author_sort Jagadeesan, G.
collection PubMed
description In the title compound, C(19)H(20)N(2)O(6), the pyrone and pyran rings adopt envelope conformations with the same common C atom as the flap, the dihedral angle between the planes of the remaining ring atoms being 68.27 (4)°. The planar atoms of the pyran ring and the diaza­cyclic ring are almost coplanar, the dihedral angle between their mean planes being 3.29 (7)°. Moreover, the planar atoms of the pyrone ring and benzene ring of the coumarin unit are also close to coplanar, the dihedral angle between their mean planes being 8.03 (9)°. The meth­oxy group lies in the plane of the benzene ring, with a dihedral angle between their mean planes of 9.4 (2)°. In the crystal, the molecules are linked by C—H⋯O hydrogen bonds resulting in sheets of mol­ecules in the ac plane.
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spelling pubmed-35698002013-02-19 14-Eth­oxy-4,6,9-trimethyl-8,12-dioxa-4,6-diaza­tetra­cyclo­[8.8.0.0(2,7).0(13,18)]octa­deca-2(7),13,15,17-tetra­ene-3,5,11-trione Jagadeesan, G. Kannan, D. Bakthadoss, M. Aravindhan, S. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(19)H(20)N(2)O(6), the pyrone and pyran rings adopt envelope conformations with the same common C atom as the flap, the dihedral angle between the planes of the remaining ring atoms being 68.27 (4)°. The planar atoms of the pyran ring and the diaza­cyclic ring are almost coplanar, the dihedral angle between their mean planes being 3.29 (7)°. Moreover, the planar atoms of the pyrone ring and benzene ring of the coumarin unit are also close to coplanar, the dihedral angle between their mean planes being 8.03 (9)°. The meth­oxy group lies in the plane of the benzene ring, with a dihedral angle between their mean planes of 9.4 (2)°. In the crystal, the molecules are linked by C—H⋯O hydrogen bonds resulting in sheets of mol­ecules in the ac plane. International Union of Crystallography 2013-01-23 /pmc/articles/PMC3569800/ /pubmed/23424546 http://dx.doi.org/10.1107/S1600536813000743 Text en © Jagadeesan et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Jagadeesan, G.
Kannan, D.
Bakthadoss, M.
Aravindhan, S.
14-Eth­oxy-4,6,9-trimethyl-8,12-dioxa-4,6-diaza­tetra­cyclo­[8.8.0.0(2,7).0(13,18)]octa­deca-2(7),13,15,17-tetra­ene-3,5,11-trione
title 14-Eth­oxy-4,6,9-trimethyl-8,12-dioxa-4,6-diaza­tetra­cyclo­[8.8.0.0(2,7).0(13,18)]octa­deca-2(7),13,15,17-tetra­ene-3,5,11-trione
title_full 14-Eth­oxy-4,6,9-trimethyl-8,12-dioxa-4,6-diaza­tetra­cyclo­[8.8.0.0(2,7).0(13,18)]octa­deca-2(7),13,15,17-tetra­ene-3,5,11-trione
title_fullStr 14-Eth­oxy-4,6,9-trimethyl-8,12-dioxa-4,6-diaza­tetra­cyclo­[8.8.0.0(2,7).0(13,18)]octa­deca-2(7),13,15,17-tetra­ene-3,5,11-trione
title_full_unstemmed 14-Eth­oxy-4,6,9-trimethyl-8,12-dioxa-4,6-diaza­tetra­cyclo­[8.8.0.0(2,7).0(13,18)]octa­deca-2(7),13,15,17-tetra­ene-3,5,11-trione
title_short 14-Eth­oxy-4,6,9-trimethyl-8,12-dioxa-4,6-diaza­tetra­cyclo­[8.8.0.0(2,7).0(13,18)]octa­deca-2(7),13,15,17-tetra­ene-3,5,11-trione
title_sort 14-eth­oxy-4,6,9-trimethyl-8,12-dioxa-4,6-diaza­tetra­cyclo­[8.8.0.0(2,7).0(13,18)]octa­deca-2(7),13,15,17-tetra­ene-3,5,11-trione
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569800/
https://www.ncbi.nlm.nih.gov/pubmed/23424546
http://dx.doi.org/10.1107/S1600536813000743
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