rac-4a,10b-cis,10b,5c-trans-5-(7-Methyl-2-oxo-2H-chromen-4-yl)-3,4,4a,5,6,10b-hexa­hydro-2H-pyrano[3,2-c]quinoline

In the racemic title compound, C(22)H(21)NO(3), the nitro­gen-containing ring of the pyran­oquinoline moiety adopts a slightly distorted half-chair conformation and the oxygen-containing ring adopts a slightly distorted chair conformation. The benzene rings make a dihedral angle of 84.97 (8)°. In th...

Descripción completa

Detalles Bibliográficos
Autores principales: Kayalvizhi, M., Vasuki, G., Samant, Shriniwas D., Sanap, Kailas K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569807/
https://www.ncbi.nlm.nih.gov/pubmed/23424553
http://dx.doi.org/10.1107/S1600536813001876
_version_ 1782258967317053440
author Kayalvizhi, M.
Vasuki, G.
Samant, Shriniwas D.
Sanap, Kailas K.
author_facet Kayalvizhi, M.
Vasuki, G.
Samant, Shriniwas D.
Sanap, Kailas K.
author_sort Kayalvizhi, M.
collection PubMed
description In the racemic title compound, C(22)H(21)NO(3), the nitro­gen-containing ring of the pyran­oquinoline moiety adopts a slightly distorted half-chair conformation and the oxygen-containing ring adopts a slightly distorted chair conformation. The benzene rings make a dihedral angle of 84.97 (8)°. In the crystal, weak C—H⋯O inter­actions link the mol­ecules into chains extending along the a-axis direction.
format Online
Article
Text
id pubmed-3569807
institution National Center for Biotechnology Information
language English
publishDate 2013
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-35698072013-02-19 rac-4a,10b-cis,10b,5c-trans-5-(7-Methyl-2-oxo-2H-chromen-4-yl)-3,4,4a,5,6,10b-hexa­hydro-2H-pyrano[3,2-c]quinoline Kayalvizhi, M. Vasuki, G. Samant, Shriniwas D. Sanap, Kailas K. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the racemic title compound, C(22)H(21)NO(3), the nitro­gen-containing ring of the pyran­oquinoline moiety adopts a slightly distorted half-chair conformation and the oxygen-containing ring adopts a slightly distorted chair conformation. The benzene rings make a dihedral angle of 84.97 (8)°. In the crystal, weak C—H⋯O inter­actions link the mol­ecules into chains extending along the a-axis direction. International Union of Crystallography 2013-01-23 /pmc/articles/PMC3569807/ /pubmed/23424553 http://dx.doi.org/10.1107/S1600536813001876 Text en © Kayalvizhi et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Kayalvizhi, M.
Vasuki, G.
Samant, Shriniwas D.
Sanap, Kailas K.
rac-4a,10b-cis,10b,5c-trans-5-(7-Methyl-2-oxo-2H-chromen-4-yl)-3,4,4a,5,6,10b-hexa­hydro-2H-pyrano[3,2-c]quinoline
title rac-4a,10b-cis,10b,5c-trans-5-(7-Methyl-2-oxo-2H-chromen-4-yl)-3,4,4a,5,6,10b-hexa­hydro-2H-pyrano[3,2-c]quinoline
title_full rac-4a,10b-cis,10b,5c-trans-5-(7-Methyl-2-oxo-2H-chromen-4-yl)-3,4,4a,5,6,10b-hexa­hydro-2H-pyrano[3,2-c]quinoline
title_fullStr rac-4a,10b-cis,10b,5c-trans-5-(7-Methyl-2-oxo-2H-chromen-4-yl)-3,4,4a,5,6,10b-hexa­hydro-2H-pyrano[3,2-c]quinoline
title_full_unstemmed rac-4a,10b-cis,10b,5c-trans-5-(7-Methyl-2-oxo-2H-chromen-4-yl)-3,4,4a,5,6,10b-hexa­hydro-2H-pyrano[3,2-c]quinoline
title_short rac-4a,10b-cis,10b,5c-trans-5-(7-Methyl-2-oxo-2H-chromen-4-yl)-3,4,4a,5,6,10b-hexa­hydro-2H-pyrano[3,2-c]quinoline
title_sort rac-4a,10b-cis,10b,5c-trans-5-(7-methyl-2-oxo-2h-chromen-4-yl)-3,4,4a,5,6,10b-hexa­hydro-2h-pyrano[3,2-c]quinoline
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569807/
https://www.ncbi.nlm.nih.gov/pubmed/23424553
http://dx.doi.org/10.1107/S1600536813001876
work_keys_str_mv AT kayalvizhim rac4a10bcis10b5ctrans57methyl2oxo2hchromen4yl344a5610bhexahydro2hpyrano32cquinoline
AT vasukig rac4a10bcis10b5ctrans57methyl2oxo2hchromen4yl344a5610bhexahydro2hpyrano32cquinoline
AT samantshriniwasd rac4a10bcis10b5ctrans57methyl2oxo2hchromen4yl344a5610bhexahydro2hpyrano32cquinoline
AT sanapkailask rac4a10bcis10b5ctrans57methyl2oxo2hchromen4yl344a5610bhexahydro2hpyrano32cquinoline

Ejemplares similares