rac-[2-(Dicyclohexylphosphanyl)phenyl](phenyl)phosphinic diisopropyl­amide–borane hemihydrate

In the title compound, C(30)H(48)BNOP(2)·0.5H(2)O, the water molecule is disordered about an inversion centre. Both phospho­rus atoms shows distortions in their tetra­hedral environments with the cyclo­hexyl substituents disordered over two orientations in a 0.851 (3):0.149 (3) occupancy ratio. The...

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Detalles Bibliográficos
Autores principales: Evans, Stephen J., Renison, C. Alicia, Williams, D. Bradley G., Muller, Alfred
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569809/
https://www.ncbi.nlm.nih.gov/pubmed/23424555
http://dx.doi.org/10.1107/S1600536813001839
Descripción
Sumario:In the title compound, C(30)H(48)BNOP(2)·0.5H(2)O, the water molecule is disordered about an inversion centre. Both phospho­rus atoms shows distortions in their tetra­hedral environments with the cyclo­hexyl substituents disordered over two orientations in a 0.851 (3):0.149 (3) occupancy ratio. The crystal structure is assembled via O—H⋯O inter­actions between pairs of phosphininc amide mol­ecules and water molecules, creating hydrogen-bonded dimers with graph-set R (2) (4)(8) along [001]. Weak C—H⋯O inter­actions are also observed.

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