rac-[2-(Dicyclohexylphosphanyl)phenyl](phenyl)phosphinic diisopropyl­amide–borane hemihydrate

In the title compound, C(30)H(48)BNOP(2)·0.5H(2)O, the water molecule is disordered about an inversion centre. Both phospho­rus atoms shows distortions in their tetra­hedral environments with the cyclo­hexyl substituents disordered over two orientations in a 0.851 (3):0.149 (3) occupancy ratio. The...

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Detalles Bibliográficos
Autores principales: Evans, Stephen J., Renison, C. Alicia, Williams, D. Bradley G., Muller, Alfred
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569809/
https://www.ncbi.nlm.nih.gov/pubmed/23424555
http://dx.doi.org/10.1107/S1600536813001839
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author Evans, Stephen J.
Renison, C. Alicia
Williams, D. Bradley G.
Muller, Alfred
author_facet Evans, Stephen J.
Renison, C. Alicia
Williams, D. Bradley G.
Muller, Alfred
author_sort Evans, Stephen J.
collection PubMed
description In the title compound, C(30)H(48)BNOP(2)·0.5H(2)O, the water molecule is disordered about an inversion centre. Both phospho­rus atoms shows distortions in their tetra­hedral environments with the cyclo­hexyl substituents disordered over two orientations in a 0.851 (3):0.149 (3) occupancy ratio. The crystal structure is assembled via O—H⋯O inter­actions between pairs of phosphininc amide mol­ecules and water molecules, creating hydrogen-bonded dimers with graph-set R (2) (4)(8) along [001]. Weak C—H⋯O inter­actions are also observed.
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spelling pubmed-35698092013-02-19 rac-[2-(Dicyclohexylphosphanyl)phenyl](phenyl)phosphinic diisopropyl­amide–borane hemihydrate Evans, Stephen J. Renison, C. Alicia Williams, D. Bradley G. Muller, Alfred Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(30)H(48)BNOP(2)·0.5H(2)O, the water molecule is disordered about an inversion centre. Both phospho­rus atoms shows distortions in their tetra­hedral environments with the cyclo­hexyl substituents disordered over two orientations in a 0.851 (3):0.149 (3) occupancy ratio. The crystal structure is assembled via O—H⋯O inter­actions between pairs of phosphininc amide mol­ecules and water molecules, creating hydrogen-bonded dimers with graph-set R (2) (4)(8) along [001]. Weak C—H⋯O inter­actions are also observed. International Union of Crystallography 2013-01-23 /pmc/articles/PMC3569809/ /pubmed/23424555 http://dx.doi.org/10.1107/S1600536813001839 Text en © Evans et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Evans, Stephen J.
Renison, C. Alicia
Williams, D. Bradley G.
Muller, Alfred
rac-[2-(Dicyclohexylphosphanyl)phenyl](phenyl)phosphinic diisopropyl­amide–borane hemihydrate
title rac-[2-(Dicyclohexylphosphanyl)phenyl](phenyl)phosphinic diisopropyl­amide–borane hemihydrate
title_full rac-[2-(Dicyclohexylphosphanyl)phenyl](phenyl)phosphinic diisopropyl­amide–borane hemihydrate
title_fullStr rac-[2-(Dicyclohexylphosphanyl)phenyl](phenyl)phosphinic diisopropyl­amide–borane hemihydrate
title_full_unstemmed rac-[2-(Dicyclohexylphosphanyl)phenyl](phenyl)phosphinic diisopropyl­amide–borane hemihydrate
title_short rac-[2-(Dicyclohexylphosphanyl)phenyl](phenyl)phosphinic diisopropyl­amide–borane hemihydrate
title_sort rac-[2-(dicyclohexylphosphanyl)phenyl](phenyl)phosphinic diisopropyl­amide–borane hemihydrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569809/
https://www.ncbi.nlm.nih.gov/pubmed/23424555
http://dx.doi.org/10.1107/S1600536813001839
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