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4-[5-(4-Chloro­phen­yl)-3-methyl-1H-pyrazol-1-yl]benzene­sulfonamide

In the title compound, C(16)H(14)ClN(3)O(2)S, the dihedral angle between the benzene and pyrazole rings is 52.75 (2)°, while that between the pyrazole and 4-chloro­phenyl rings is 54.0 (3)°. The terminal sulfonamide group adopts an approximately tetra­hedral geometry about the S atom with a C—S—N an...

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Detalles Bibliográficos
Autores principales: Farrukh, Muhammad A., Mohamed, Shaaban K., Ahmed, Maqsood, Marzouk, Adel A., El-Moghazy, Samir M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569817/
https://www.ncbi.nlm.nih.gov/pubmed/23424563
http://dx.doi.org/10.1107/S1600536813002134
Descripción
Sumario:In the title compound, C(16)H(14)ClN(3)O(2)S, the dihedral angle between the benzene and pyrazole rings is 52.75 (2)°, while that between the pyrazole and 4-chloro­phenyl rings is 54.0 (3)°. The terminal sulfonamide group adopts an approximately tetra­hedral geometry about the S atom with a C—S—N angle of 108.33 (10)°. In the crystal, pairs of N—H⋯N hydrogen bonds lead to the formation of inversion dimers. These dimers are linked via a second pair of N—H⋯N hydrogen bonds and C—H⋯O interactions, forming a two-dimensional network lying parallel to the bc plane. The two-dimensional networks are linked via C—H⋯Cl interactions, forming a three-dimensional structure.