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4-[5-(4-Chloro­phen­yl)-3-methyl-1H-pyrazol-1-yl]benzene­sulfonamide

In the title compound, C(16)H(14)ClN(3)O(2)S, the dihedral angle between the benzene and pyrazole rings is 52.75 (2)°, while that between the pyrazole and 4-chloro­phenyl rings is 54.0 (3)°. The terminal sulfonamide group adopts an approximately tetra­hedral geometry about the S atom with a C—S—N an...

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Autores principales: Farrukh, Muhammad A., Mohamed, Shaaban K., Ahmed, Maqsood, Marzouk, Adel A., El-Moghazy, Samir M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569817/
https://www.ncbi.nlm.nih.gov/pubmed/23424563
http://dx.doi.org/10.1107/S1600536813002134
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author Farrukh, Muhammad A.
Mohamed, Shaaban K.
Ahmed, Maqsood
Marzouk, Adel A.
El-Moghazy, Samir M.
author_facet Farrukh, Muhammad A.
Mohamed, Shaaban K.
Ahmed, Maqsood
Marzouk, Adel A.
El-Moghazy, Samir M.
author_sort Farrukh, Muhammad A.
collection PubMed
description In the title compound, C(16)H(14)ClN(3)O(2)S, the dihedral angle between the benzene and pyrazole rings is 52.75 (2)°, while that between the pyrazole and 4-chloro­phenyl rings is 54.0 (3)°. The terminal sulfonamide group adopts an approximately tetra­hedral geometry about the S atom with a C—S—N angle of 108.33 (10)°. In the crystal, pairs of N—H⋯N hydrogen bonds lead to the formation of inversion dimers. These dimers are linked via a second pair of N—H⋯N hydrogen bonds and C—H⋯O interactions, forming a two-dimensional network lying parallel to the bc plane. The two-dimensional networks are linked via C—H⋯Cl interactions, forming a three-dimensional structure.
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spelling pubmed-35698172013-02-19 4-[5-(4-Chloro­phen­yl)-3-methyl-1H-pyrazol-1-yl]benzene­sulfonamide Farrukh, Muhammad A. Mohamed, Shaaban K. Ahmed, Maqsood Marzouk, Adel A. El-Moghazy, Samir M. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(16)H(14)ClN(3)O(2)S, the dihedral angle between the benzene and pyrazole rings is 52.75 (2)°, while that between the pyrazole and 4-chloro­phenyl rings is 54.0 (3)°. The terminal sulfonamide group adopts an approximately tetra­hedral geometry about the S atom with a C—S—N angle of 108.33 (10)°. In the crystal, pairs of N—H⋯N hydrogen bonds lead to the formation of inversion dimers. These dimers are linked via a second pair of N—H⋯N hydrogen bonds and C—H⋯O interactions, forming a two-dimensional network lying parallel to the bc plane. The two-dimensional networks are linked via C—H⋯Cl interactions, forming a three-dimensional structure. International Union of Crystallography 2013-01-26 /pmc/articles/PMC3569817/ /pubmed/23424563 http://dx.doi.org/10.1107/S1600536813002134 Text en © Farrukh et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Farrukh, Muhammad A.
Mohamed, Shaaban K.
Ahmed, Maqsood
Marzouk, Adel A.
El-Moghazy, Samir M.
4-[5-(4-Chloro­phen­yl)-3-methyl-1H-pyrazol-1-yl]benzene­sulfonamide
title 4-[5-(4-Chloro­phen­yl)-3-methyl-1H-pyrazol-1-yl]benzene­sulfonamide
title_full 4-[5-(4-Chloro­phen­yl)-3-methyl-1H-pyrazol-1-yl]benzene­sulfonamide
title_fullStr 4-[5-(4-Chloro­phen­yl)-3-methyl-1H-pyrazol-1-yl]benzene­sulfonamide
title_full_unstemmed 4-[5-(4-Chloro­phen­yl)-3-methyl-1H-pyrazol-1-yl]benzene­sulfonamide
title_short 4-[5-(4-Chloro­phen­yl)-3-methyl-1H-pyrazol-1-yl]benzene­sulfonamide
title_sort 4-[5-(4-chloro­phen­yl)-3-methyl-1h-pyrazol-1-yl]benzene­sulfonamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569817/
https://www.ncbi.nlm.nih.gov/pubmed/23424563
http://dx.doi.org/10.1107/S1600536813002134
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