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9-(3,4-Dimeth­oxy­phen­yl)-3,3,6,6-tetra­methyl-1,2,3,4,5,6,7,8,9,10-deca­hydro­acridine-1,8-dione

The asymmetric unit of the title compound, C(25)H(31)NO(4), contains two independent mol­ecules. In one mol­ecule, the benzene ring and an attached meth­oxy group were refined as disordered over two sets of sites in a 0.65 (4): 0.35 (4) ratio. In both mol­ecules, the central ring of the acridinedion...

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Autores principales: Kant, Rajni, Gupta, Vivek K., Kapoor, Kamini, Patil, D. R., Chandam, D. R., Deshmukh, Madhukar B.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569818/
https://www.ncbi.nlm.nih.gov/pubmed/23424564
http://dx.doi.org/10.1107/S1600536813002250
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author Kant, Rajni
Gupta, Vivek K.
Kapoor, Kamini
Patil, D. R.
Chandam, D. R.
Deshmukh, Madhukar B.
author_facet Kant, Rajni
Gupta, Vivek K.
Kapoor, Kamini
Patil, D. R.
Chandam, D. R.
Deshmukh, Madhukar B.
author_sort Kant, Rajni
collection PubMed
description The asymmetric unit of the title compound, C(25)H(31)NO(4), contains two independent mol­ecules. In one mol­ecule, the benzene ring and an attached meth­oxy group were refined as disordered over two sets of sites in a 0.65 (4): 0.35 (4) ratio. In both mol­ecules, the central ring of the acridinedione system adopts a flattened boat conformation. The four essentially planar atoms of this ring [maximum deviations = 0.006 (5) Å in both mol­ecules] forms dihedral angles of 86.8 (2) and 87.6 (2)°, respectively, with the major and minor components in the disordered benzene ring and 87.3 (2)° with the benzene ring in the fully ordered mol­ecule. The two outer rings of the acridinedione system adopt sofa conformations in both mol­ecules. In the crystal, N—H⋯O hydrogen bonds form two independent chains along [100]. C—H⋯O hydrogen bonds link the chains, forming a three-dimensional network.
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spelling pubmed-35698182013-02-19 9-(3,4-Dimeth­oxy­phen­yl)-3,3,6,6-tetra­methyl-1,2,3,4,5,6,7,8,9,10-deca­hydro­acridine-1,8-dione Kant, Rajni Gupta, Vivek K. Kapoor, Kamini Patil, D. R. Chandam, D. R. Deshmukh, Madhukar B. Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(25)H(31)NO(4), contains two independent mol­ecules. In one mol­ecule, the benzene ring and an attached meth­oxy group were refined as disordered over two sets of sites in a 0.65 (4): 0.35 (4) ratio. In both mol­ecules, the central ring of the acridinedione system adopts a flattened boat conformation. The four essentially planar atoms of this ring [maximum deviations = 0.006 (5) Å in both mol­ecules] forms dihedral angles of 86.8 (2) and 87.6 (2)°, respectively, with the major and minor components in the disordered benzene ring and 87.3 (2)° with the benzene ring in the fully ordered mol­ecule. The two outer rings of the acridinedione system adopt sofa conformations in both mol­ecules. In the crystal, N—H⋯O hydrogen bonds form two independent chains along [100]. C—H⋯O hydrogen bonds link the chains, forming a three-dimensional network. International Union of Crystallography 2013-01-26 /pmc/articles/PMC3569818/ /pubmed/23424564 http://dx.doi.org/10.1107/S1600536813002250 Text en © Kant et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Kant, Rajni
Gupta, Vivek K.
Kapoor, Kamini
Patil, D. R.
Chandam, D. R.
Deshmukh, Madhukar B.
9-(3,4-Dimeth­oxy­phen­yl)-3,3,6,6-tetra­methyl-1,2,3,4,5,6,7,8,9,10-deca­hydro­acridine-1,8-dione
title 9-(3,4-Dimeth­oxy­phen­yl)-3,3,6,6-tetra­methyl-1,2,3,4,5,6,7,8,9,10-deca­hydro­acridine-1,8-dione
title_full 9-(3,4-Dimeth­oxy­phen­yl)-3,3,6,6-tetra­methyl-1,2,3,4,5,6,7,8,9,10-deca­hydro­acridine-1,8-dione
title_fullStr 9-(3,4-Dimeth­oxy­phen­yl)-3,3,6,6-tetra­methyl-1,2,3,4,5,6,7,8,9,10-deca­hydro­acridine-1,8-dione
title_full_unstemmed 9-(3,4-Dimeth­oxy­phen­yl)-3,3,6,6-tetra­methyl-1,2,3,4,5,6,7,8,9,10-deca­hydro­acridine-1,8-dione
title_short 9-(3,4-Dimeth­oxy­phen­yl)-3,3,6,6-tetra­methyl-1,2,3,4,5,6,7,8,9,10-deca­hydro­acridine-1,8-dione
title_sort 9-(3,4-dimeth­oxy­phen­yl)-3,3,6,6-tetra­methyl-1,2,3,4,5,6,7,8,9,10-deca­hydro­acridine-1,8-dione
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569818/
https://www.ncbi.nlm.nih.gov/pubmed/23424564
http://dx.doi.org/10.1107/S1600536813002250
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