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The charge-transfer complex 1-aminoanthraquinone–7,7′,8,8′-tetracyanoquinodimethane (1/1)
The reaction of 1-aminoanthraquinone with 7,7′,8,8′-tetracyanoquinodimethane yielded the title charge-transfer complex, C(14)H(9)NO(2)·C(12)H(4)N(4). The molecules have maximum deviations from the mean planes through the non-H atoms of 0.0769 (14) Å for an oxo O atom and 0.1175 (17) Å for a cyan...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569820/ https://www.ncbi.nlm.nih.gov/pubmed/23424566 http://dx.doi.org/10.1107/S1600536813002195 |
Sumario: | The reaction of 1-aminoanthraquinone with 7,7′,8,8′-tetracyanoquinodimethane yielded the title charge-transfer complex, C(14)H(9)NO(2)·C(12)H(4)N(4). The molecules have maximum deviations from the mean planes through the non-H atoms of 0.0769 (14) Å for an oxo O atom and 0.1175 (17) Å for a cyano N atom, respectively. The dihedral angle between the two planes is 3.55 (3)°. In the crystal, molecules are stacked into columns along the a-axis direction. Pairs of N—H⋯N and N—H⋯O interactions connect the molecules perpendicular to the stacking direction. Additionally, an intramolecular N—H⋯O hydrogen-bond interaction is observed for 1-aminoanthraquinone. |
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