The charge-transfer complex 1-amino­anthraquinone–7,7′,8,8′-tetra­cyano­quinodimethane (1/1)

The reaction of 1-amino­anthraquinone with 7,7′,8,8′-tetra­cyano­quinodimethane yielded the title charge-transfer complex, C(14)H(9)NO(2)·C(12)H(4)N(4). The mol­ecules have maximum deviations from the mean planes through the non-H atoms of 0.0769 (14) Å for an oxo O atom and 0.1175 (17) Å for a cyan...

Descripción completa

Detalles Bibliográficos
Autores principales: de Oliveira, Adriano Bof, Beck, Johannes, Daniels, Jörg, Santos, Jaciara Nascimento, Feitosa, Bárbara Regina Santos
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569820/
https://www.ncbi.nlm.nih.gov/pubmed/23424566
http://dx.doi.org/10.1107/S1600536813002195
_version_ 1782258970420838400
author de Oliveira, Adriano Bof
Beck, Johannes
Daniels, Jörg
Santos, Jaciara Nascimento
Feitosa, Bárbara Regina Santos
author_facet de Oliveira, Adriano Bof
Beck, Johannes
Daniels, Jörg
Santos, Jaciara Nascimento
Feitosa, Bárbara Regina Santos
author_sort de Oliveira, Adriano Bof
collection PubMed
description The reaction of 1-amino­anthraquinone with 7,7′,8,8′-tetra­cyano­quinodimethane yielded the title charge-transfer complex, C(14)H(9)NO(2)·C(12)H(4)N(4). The mol­ecules have maximum deviations from the mean planes through the non-H atoms of 0.0769 (14) Å for an oxo O atom and 0.1175 (17) Å for a cyano N atom, respectively. The dihedral angle between the two planes is 3.55 (3)°. In the crystal, mol­ecules are stacked into columns along the a-axis direction. Pairs of N—H⋯N and N—H⋯O inter­actions connect the mol­ecules perpendicular to the stacking direction. Additionally, an intra­molecular N—H⋯O hydrogen-bond inter­action is observed for 1-amino­anthraquinone.
format Online
Article
Text
id pubmed-3569820
institution National Center for Biotechnology Information
language English
publishDate 2013
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-35698202013-02-19 The charge-transfer complex 1-amino­anthraquinone–7,7′,8,8′-tetra­cyano­quinodimethane (1/1) de Oliveira, Adriano Bof Beck, Johannes Daniels, Jörg Santos, Jaciara Nascimento Feitosa, Bárbara Regina Santos Acta Crystallogr Sect E Struct Rep Online Organic Papers The reaction of 1-amino­anthraquinone with 7,7′,8,8′-tetra­cyano­quinodimethane yielded the title charge-transfer complex, C(14)H(9)NO(2)·C(12)H(4)N(4). The mol­ecules have maximum deviations from the mean planes through the non-H atoms of 0.0769 (14) Å for an oxo O atom and 0.1175 (17) Å for a cyano N atom, respectively. The dihedral angle between the two planes is 3.55 (3)°. In the crystal, mol­ecules are stacked into columns along the a-axis direction. Pairs of N—H⋯N and N—H⋯O inter­actions connect the mol­ecules perpendicular to the stacking direction. Additionally, an intra­molecular N—H⋯O hydrogen-bond inter­action is observed for 1-amino­anthraquinone. International Union of Crystallography 2013-01-26 /pmc/articles/PMC3569820/ /pubmed/23424566 http://dx.doi.org/10.1107/S1600536813002195 Text en © Oliveira et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
de Oliveira, Adriano Bof
Beck, Johannes
Daniels, Jörg
Santos, Jaciara Nascimento
Feitosa, Bárbara Regina Santos
The charge-transfer complex 1-amino­anthraquinone–7,7′,8,8′-tetra­cyano­quinodimethane (1/1)
title The charge-transfer complex 1-amino­anthraquinone–7,7′,8,8′-tetra­cyano­quinodimethane (1/1)
title_full The charge-transfer complex 1-amino­anthraquinone–7,7′,8,8′-tetra­cyano­quinodimethane (1/1)
title_fullStr The charge-transfer complex 1-amino­anthraquinone–7,7′,8,8′-tetra­cyano­quinodimethane (1/1)
title_full_unstemmed The charge-transfer complex 1-amino­anthraquinone–7,7′,8,8′-tetra­cyano­quinodimethane (1/1)
title_short The charge-transfer complex 1-amino­anthraquinone–7,7′,8,8′-tetra­cyano­quinodimethane (1/1)
title_sort charge-transfer complex 1-amino­anthraquinone–7,7′,8,8′-tetra­cyano­quinodimethane (1/1)
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569820/
https://www.ncbi.nlm.nih.gov/pubmed/23424566
http://dx.doi.org/10.1107/S1600536813002195
work_keys_str_mv AT deoliveiraadrianobof thechargetransfercomplex1aminoanthraquinone7788tetracyanoquinodimethane11
AT beckjohannes thechargetransfercomplex1aminoanthraquinone7788tetracyanoquinodimethane11
AT danielsjorg thechargetransfercomplex1aminoanthraquinone7788tetracyanoquinodimethane11
AT santosjaciaranascimento thechargetransfercomplex1aminoanthraquinone7788tetracyanoquinodimethane11
AT feitosabarbarareginasantos thechargetransfercomplex1aminoanthraquinone7788tetracyanoquinodimethane11
AT deoliveiraadrianobof chargetransfercomplex1aminoanthraquinone7788tetracyanoquinodimethane11
AT beckjohannes chargetransfercomplex1aminoanthraquinone7788tetracyanoquinodimethane11
AT danielsjorg chargetransfercomplex1aminoanthraquinone7788tetracyanoquinodimethane11
AT santosjaciaranascimento chargetransfercomplex1aminoanthraquinone7788tetracyanoquinodimethane11
AT feitosabarbarareginasantos chargetransfercomplex1aminoanthraquinone7788tetracyanoquinodimethane11

Ejemplares similares