Acetonyltriphenyl­phospho­nium nitrate

Crystals of the title salt, C(21)H(20)OP(+)·NO(3) (−), are composed of acetonyltriphenyl­phospho­nium cations and nitrate anions that mainly inter­act through electrostatic forces. The P atom in the cation has a slightly distorted tetra­hedral environment, with C—P—C angles ranging from 104.79 (7) t...

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Detalles Bibliográficos
Autores principales: Diop, Tidiane, Diop, Libasse, Kučeráková, Monika, Dušek, Michal
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569822/
https://www.ncbi.nlm.nih.gov/pubmed/23424568
http://dx.doi.org/10.1107/S1600536813002110
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author Diop, Tidiane
Diop, Libasse
Kučeráková, Monika
Dušek, Michal
author_facet Diop, Tidiane
Diop, Libasse
Kučeráková, Monika
Dušek, Michal
author_sort Diop, Tidiane
collection PubMed
description Crystals of the title salt, C(21)H(20)OP(+)·NO(3) (−), are composed of acetonyltriphenyl­phospho­nium cations and nitrate anions that mainly inter­act through electrostatic forces. The P atom in the cation has a slightly distorted tetra­hedral environment, with C—P—C angles ranging from 104.79 (7) to 112.59 (6)°. The sum of O—N—O angles of the nitrate anion is 359.99°, reflecting its trigonal–planar character. C—H⋯O hydrogen bonds help to consolidate the crystal packing.
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spelling pubmed-35698222013-02-19 Acetonyltriphenyl­phospho­nium nitrate Diop, Tidiane Diop, Libasse Kučeráková, Monika Dušek, Michal Acta Crystallogr Sect E Struct Rep Online Organic Papers Crystals of the title salt, C(21)H(20)OP(+)·NO(3) (−), are composed of acetonyltriphenyl­phospho­nium cations and nitrate anions that mainly inter­act through electrostatic forces. The P atom in the cation has a slightly distorted tetra­hedral environment, with C—P—C angles ranging from 104.79 (7) to 112.59 (6)°. The sum of O—N—O angles of the nitrate anion is 359.99°, reflecting its trigonal–planar character. C—H⋯O hydrogen bonds help to consolidate the crystal packing. International Union of Crystallography 2013-01-31 /pmc/articles/PMC3569822/ /pubmed/23424568 http://dx.doi.org/10.1107/S1600536813002110 Text en © Diop et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Diop, Tidiane
Diop, Libasse
Kučeráková, Monika
Dušek, Michal
Acetonyltriphenyl­phospho­nium nitrate
title Acetonyltriphenyl­phospho­nium nitrate
title_full Acetonyltriphenyl­phospho­nium nitrate
title_fullStr Acetonyltriphenyl­phospho­nium nitrate
title_full_unstemmed Acetonyltriphenyl­phospho­nium nitrate
title_short Acetonyltriphenyl­phospho­nium nitrate
title_sort acetonyltriphenyl­phospho­nium nitrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569822/
https://www.ncbi.nlm.nih.gov/pubmed/23424568
http://dx.doi.org/10.1107/S1600536813002110
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AT dioplibasse acetonyltriphenylphosphoniumnitrate
AT kucerakovamonika acetonyltriphenylphosphoniumnitrate
AT dusekmichal acetonyltriphenylphosphoniumnitrate

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