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Phenyl acridine-9-carboxylate
The acridine ring system and the benzene ring in the title compound, C(20)H(13)NO(2), are oriented at a dihedral angle of 6.4 (2)°. The carboxyl group is twisted at an angle of 83.6 (2)° relative to the acridine skeleton. The molecules in the crystal are arranged in stacks along the b axis, with tw...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569824/ https://www.ncbi.nlm.nih.gov/pubmed/23424570 http://dx.doi.org/10.1107/S1600536813002055 |
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author | Wera, Michał Trzybiński, Damian Krzymiński, Karol Błażejowski, Jerzy |
author_facet | Wera, Michał Trzybiński, Damian Krzymiński, Karol Błażejowski, Jerzy |
author_sort | Wera, Michał |
collection | PubMed |
description | The acridine ring system and the benzene ring in the title compound, C(20)H(13)NO(2), are oriented at a dihedral angle of 6.4 (2)°. The carboxyl group is twisted at an angle of 83.6 (2)° relative to the acridine skeleton. The molecules in the crystal are arranged in stacks along the b axis, with two of the acridine rings involved in multiple π–π interactions [centroid–centroid distances in the range 3.536 (2)–3.894 (2) Å]. Stacks arranged parallel are linked via C—H⋯π interactions, forming layers in the ac plane that are in contact with adjacent, inversely oriented layers via other C—H⋯π interactions, giving rise to double layers. The inversely oriented double layers interact dispersively. The acridine units are parallel within the parallel-oriented stacks, but inclined at an angle of 79.6 (2)° in the inversely oriented stacks. |
format | Online Article Text |
id | pubmed-3569824 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-35698242013-02-19 Phenyl acridine-9-carboxylate Wera, Michał Trzybiński, Damian Krzymiński, Karol Błażejowski, Jerzy Acta Crystallogr Sect E Struct Rep Online Organic Papers The acridine ring system and the benzene ring in the title compound, C(20)H(13)NO(2), are oriented at a dihedral angle of 6.4 (2)°. The carboxyl group is twisted at an angle of 83.6 (2)° relative to the acridine skeleton. The molecules in the crystal are arranged in stacks along the b axis, with two of the acridine rings involved in multiple π–π interactions [centroid–centroid distances in the range 3.536 (2)–3.894 (2) Å]. Stacks arranged parallel are linked via C—H⋯π interactions, forming layers in the ac plane that are in contact with adjacent, inversely oriented layers via other C—H⋯π interactions, giving rise to double layers. The inversely oriented double layers interact dispersively. The acridine units are parallel within the parallel-oriented stacks, but inclined at an angle of 79.6 (2)° in the inversely oriented stacks. International Union of Crystallography 2013-01-31 /pmc/articles/PMC3569824/ /pubmed/23424570 http://dx.doi.org/10.1107/S1600536813002055 Text en © Wera et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Wera, Michał Trzybiński, Damian Krzymiński, Karol Błażejowski, Jerzy Phenyl acridine-9-carboxylate |
title | Phenyl acridine-9-carboxylate |
title_full | Phenyl acridine-9-carboxylate |
title_fullStr | Phenyl acridine-9-carboxylate |
title_full_unstemmed | Phenyl acridine-9-carboxylate |
title_short | Phenyl acridine-9-carboxylate |
title_sort | phenyl acridine-9-carboxylate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569824/ https://www.ncbi.nlm.nih.gov/pubmed/23424570 http://dx.doi.org/10.1107/S1600536813002055 |
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