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Phenyl acridine-9-carboxyl­ate

The acridine ring system and the benzene ring in the title compound, C(20)H(13)NO(2), are oriented at a dihedral angle of 6.4 (2)°. The carboxyl group is twisted at an angle of 83.6 (2)° relative to the acridine skeleton. The mol­ecules in the crystal are arranged in stacks along the b axis, with tw...

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Autores principales: Wera, Michał, Trzybiński, Damian, Krzymiński, Karol, Błażejowski, Jerzy
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569824/
https://www.ncbi.nlm.nih.gov/pubmed/23424570
http://dx.doi.org/10.1107/S1600536813002055
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author Wera, Michał
Trzybiński, Damian
Krzymiński, Karol
Błażejowski, Jerzy
author_facet Wera, Michał
Trzybiński, Damian
Krzymiński, Karol
Błażejowski, Jerzy
author_sort Wera, Michał
collection PubMed
description The acridine ring system and the benzene ring in the title compound, C(20)H(13)NO(2), are oriented at a dihedral angle of 6.4 (2)°. The carboxyl group is twisted at an angle of 83.6 (2)° relative to the acridine skeleton. The mol­ecules in the crystal are arranged in stacks along the b axis, with two of the acridine rings involved in multiple π–π inter­actions [centroid–centroid distances in the range 3.536 (2)–3.894 (2) Å]. Stacks arranged parallel are linked via C—H⋯π inter­actions, forming layers in the ac plane that are in contact with adjacent, inversely oriented layers via other C—H⋯π inter­actions, giving rise to double layers. The inversely oriented double layers inter­act dispersively. The acridine units are parallel within the parallel-oriented stacks, but inclined at an angle of 79.6 (2)° in the inversely oriented stacks.
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spelling pubmed-35698242013-02-19 Phenyl acridine-9-carboxyl­ate Wera, Michał Trzybiński, Damian Krzymiński, Karol Błażejowski, Jerzy Acta Crystallogr Sect E Struct Rep Online Organic Papers The acridine ring system and the benzene ring in the title compound, C(20)H(13)NO(2), are oriented at a dihedral angle of 6.4 (2)°. The carboxyl group is twisted at an angle of 83.6 (2)° relative to the acridine skeleton. The mol­ecules in the crystal are arranged in stacks along the b axis, with two of the acridine rings involved in multiple π–π inter­actions [centroid–centroid distances in the range 3.536 (2)–3.894 (2) Å]. Stacks arranged parallel are linked via C—H⋯π inter­actions, forming layers in the ac plane that are in contact with adjacent, inversely oriented layers via other C—H⋯π inter­actions, giving rise to double layers. The inversely oriented double layers inter­act dispersively. The acridine units are parallel within the parallel-oriented stacks, but inclined at an angle of 79.6 (2)° in the inversely oriented stacks. International Union of Crystallography 2013-01-31 /pmc/articles/PMC3569824/ /pubmed/23424570 http://dx.doi.org/10.1107/S1600536813002055 Text en © Wera et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Wera, Michał
Trzybiński, Damian
Krzymiński, Karol
Błażejowski, Jerzy
Phenyl acridine-9-carboxyl­ate
title Phenyl acridine-9-carboxyl­ate
title_full Phenyl acridine-9-carboxyl­ate
title_fullStr Phenyl acridine-9-carboxyl­ate
title_full_unstemmed Phenyl acridine-9-carboxyl­ate
title_short Phenyl acridine-9-carboxyl­ate
title_sort phenyl acridine-9-carboxyl­ate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569824/
https://www.ncbi.nlm.nih.gov/pubmed/23424570
http://dx.doi.org/10.1107/S1600536813002055
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