3β-Acet­oxy-19-hy­droxy-Δ(5)-pregnen-20-one

In the title compound, C(23)H(34)O(4), the C/D and D/E rings are trans fused and the A/B ring possesses an anti fusion. The two cyclo­hexane rings adopt a chair conformation while the cyclo­hexene ring exhibits a half-chair conformation. The cyclo­pentane ring displays an envelope conformation with...

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Autores principales: Meier zu Greffen, Aike, Kranz, Darius P., Neudörfl, Jörg-M., Schmalz, Hans-Günther
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569832/
https://www.ncbi.nlm.nih.gov/pubmed/23424578
http://dx.doi.org/10.1107/S1600536813002493
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author Meier zu Greffen, Aike
Kranz, Darius P.
Neudörfl, Jörg-M.
Schmalz, Hans-Günther
author_facet Meier zu Greffen, Aike
Kranz, Darius P.
Neudörfl, Jörg-M.
Schmalz, Hans-Günther
author_sort Meier zu Greffen, Aike
collection PubMed
description In the title compound, C(23)H(34)O(4), the C/D and D/E rings are trans fused and the A/B ring possesses an anti fusion. The two cyclo­hexane rings adopt a chair conformation while the cyclo­hexene ring exhibits a half-chair conformation. The cyclo­pentane ring displays an envelope conformation with the C atom bearing the methyl group as the flap. In the crystal, the mol­ecules are linked by O—H⋯O hydrogen bonds, forming chains along the b axis.
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spelling pubmed-35698322013-02-19 3β-Acet­oxy-19-hy­droxy-Δ(5)-pregnen-20-one Meier zu Greffen, Aike Kranz, Darius P. Neudörfl, Jörg-M. Schmalz, Hans-Günther Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(23)H(34)O(4), the C/D and D/E rings are trans fused and the A/B ring possesses an anti fusion. The two cyclo­hexane rings adopt a chair conformation while the cyclo­hexene ring exhibits a half-chair conformation. The cyclo­pentane ring displays an envelope conformation with the C atom bearing the methyl group as the flap. In the crystal, the mol­ecules are linked by O—H⋯O hydrogen bonds, forming chains along the b axis. International Union of Crystallography 2013-01-31 /pmc/articles/PMC3569832/ /pubmed/23424578 http://dx.doi.org/10.1107/S1600536813002493 Text en © Meier zu Greffen et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Meier zu Greffen, Aike
Kranz, Darius P.
Neudörfl, Jörg-M.
Schmalz, Hans-Günther
3β-Acet­oxy-19-hy­droxy-Δ(5)-pregnen-20-one
title 3β-Acet­oxy-19-hy­droxy-Δ(5)-pregnen-20-one
title_full 3β-Acet­oxy-19-hy­droxy-Δ(5)-pregnen-20-one
title_fullStr 3β-Acet­oxy-19-hy­droxy-Δ(5)-pregnen-20-one
title_full_unstemmed 3β-Acet­oxy-19-hy­droxy-Δ(5)-pregnen-20-one
title_short 3β-Acet­oxy-19-hy­droxy-Δ(5)-pregnen-20-one
title_sort 3β-acet­oxy-19-hy­droxy-δ(5)-pregnen-20-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569832/
https://www.ncbi.nlm.nih.gov/pubmed/23424578
http://dx.doi.org/10.1107/S1600536813002493
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