(1S,3aS,4S,7aS)-Ethyl 1-benzyl-2-(4-meth­oxy­benz­yl)-6,7-dimethyl-3-oxo-2,3,3a,4,5,7a-hexa­hydro-1H-isoindole-4-carboxyl­ate dichloro­methane monosolvate

In the title compound, C(28)H(33)NO(4)·CH(2)Cl(2), the pyrrolidone ring adopts a twisted envelope conformation and the cyclo­hexene has a half-chair conformation. In the crystal, weak C—H⋯O hydrogen bonds link the components into chains along [100].

Detalles Bibliográficos
Autores principales: Lin, Benguo, Wu, Jin-Long
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569834/
https://www.ncbi.nlm.nih.gov/pubmed/23424580
http://dx.doi.org/10.1107/S1600536813002560
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author Lin, Benguo
Wu, Jin-Long
author_facet Lin, Benguo
Wu, Jin-Long
author_sort Lin, Benguo
collection PubMed
description In the title compound, C(28)H(33)NO(4)·CH(2)Cl(2), the pyrrolidone ring adopts a twisted envelope conformation and the cyclo­hexene has a half-chair conformation. In the crystal, weak C—H⋯O hydrogen bonds link the components into chains along [100].
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spelling pubmed-35698342013-02-19 (1S,3aS,4S,7aS)-Ethyl 1-benzyl-2-(4-meth­oxy­benz­yl)-6,7-dimethyl-3-oxo-2,3,3a,4,5,7a-hexa­hydro-1H-isoindole-4-carboxyl­ate dichloro­methane monosolvate Lin, Benguo Wu, Jin-Long Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(28)H(33)NO(4)·CH(2)Cl(2), the pyrrolidone ring adopts a twisted envelope conformation and the cyclo­hexene has a half-chair conformation. In the crystal, weak C—H⋯O hydrogen bonds link the components into chains along [100]. International Union of Crystallography 2013-01-31 /pmc/articles/PMC3569834/ /pubmed/23424580 http://dx.doi.org/10.1107/S1600536813002560 Text en © Lin and Wu 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Lin, Benguo
Wu, Jin-Long
(1S,3aS,4S,7aS)-Ethyl 1-benzyl-2-(4-meth­oxy­benz­yl)-6,7-dimethyl-3-oxo-2,3,3a,4,5,7a-hexa­hydro-1H-isoindole-4-carboxyl­ate dichloro­methane monosolvate
title (1S,3aS,4S,7aS)-Ethyl 1-benzyl-2-(4-meth­oxy­benz­yl)-6,7-dimethyl-3-oxo-2,3,3a,4,5,7a-hexa­hydro-1H-isoindole-4-carboxyl­ate dichloro­methane monosolvate
title_full (1S,3aS,4S,7aS)-Ethyl 1-benzyl-2-(4-meth­oxy­benz­yl)-6,7-dimethyl-3-oxo-2,3,3a,4,5,7a-hexa­hydro-1H-isoindole-4-carboxyl­ate dichloro­methane monosolvate
title_fullStr (1S,3aS,4S,7aS)-Ethyl 1-benzyl-2-(4-meth­oxy­benz­yl)-6,7-dimethyl-3-oxo-2,3,3a,4,5,7a-hexa­hydro-1H-isoindole-4-carboxyl­ate dichloro­methane monosolvate
title_full_unstemmed (1S,3aS,4S,7aS)-Ethyl 1-benzyl-2-(4-meth­oxy­benz­yl)-6,7-dimethyl-3-oxo-2,3,3a,4,5,7a-hexa­hydro-1H-isoindole-4-carboxyl­ate dichloro­methane monosolvate
title_short (1S,3aS,4S,7aS)-Ethyl 1-benzyl-2-(4-meth­oxy­benz­yl)-6,7-dimethyl-3-oxo-2,3,3a,4,5,7a-hexa­hydro-1H-isoindole-4-carboxyl­ate dichloro­methane monosolvate
title_sort (1s,3as,4s,7as)-ethyl 1-benzyl-2-(4-meth­oxy­benz­yl)-6,7-dimethyl-3-oxo-2,3,3a,4,5,7a-hexa­hydro-1h-isoindole-4-carboxyl­ate dichloro­methane monosolvate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569834/
https://www.ncbi.nlm.nih.gov/pubmed/23424580
http://dx.doi.org/10.1107/S1600536813002560
work_keys_str_mv AT linbenguo 1s3as4s7asethyl1benzyl24methoxybenzyl67dimethyl3oxo233a457ahexahydro1hisoindole4carboxylatedichloromethanemonosolvate
AT wujinlong 1s3as4s7asethyl1benzyl24methoxybenzyl67dimethyl3oxo233a457ahexahydro1hisoindole4carboxylatedichloromethanemonosolvate

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