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An effective oxidation approach for luminescence enhancement in CdS quantum dots by H(2)O(2)
The effects of surface passivation on the photoluminescence (PL) properties of CdS nanoparticles oxidized by straightforward H(2)O(2) injection were examined. Compared to pristine cadmium sulfide nanocrystals (quantum efficiency ≅ 0.1%), the surface-passivated CdS nanoparticles showed significantly...
Autores principales: | , , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Springer
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3570443/ https://www.ncbi.nlm.nih.gov/pubmed/23234569 http://dx.doi.org/10.1186/1556-276X-7-672 |
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author | Lee, Woojin Kim, Hoechang Jung, Dae-Ryong Kim, Jongmin Nahm, Changwoo Lee, Junhee Kang, Suji Lee, Byungho Park, Byungwoo |
author_facet | Lee, Woojin Kim, Hoechang Jung, Dae-Ryong Kim, Jongmin Nahm, Changwoo Lee, Junhee Kang, Suji Lee, Byungho Park, Byungwoo |
author_sort | Lee, Woojin |
collection | PubMed |
description | The effects of surface passivation on the photoluminescence (PL) properties of CdS nanoparticles oxidized by straightforward H(2)O(2) injection were examined. Compared to pristine cadmium sulfide nanocrystals (quantum efficiency ≅ 0.1%), the surface-passivated CdS nanoparticles showed significantly enhanced luminescence properties (quantum efficiency ≅ 20%). The surface passivation by H(2)O(2) injection was characterized using X-ray photoelectron spectroscopy, X-ray diffraction, and time-resolved PL. The photoluminescence enhancement is due to the two-order increase in the radiative recombination rate by the sulfate passivation layer. |
format | Online Article Text |
id | pubmed-3570443 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | Springer |
record_format | MEDLINE/PubMed |
spelling | pubmed-35704432013-02-13 An effective oxidation approach for luminescence enhancement in CdS quantum dots by H(2)O(2) Lee, Woojin Kim, Hoechang Jung, Dae-Ryong Kim, Jongmin Nahm, Changwoo Lee, Junhee Kang, Suji Lee, Byungho Park, Byungwoo Nanoscale Res Lett Nano Express The effects of surface passivation on the photoluminescence (PL) properties of CdS nanoparticles oxidized by straightforward H(2)O(2) injection were examined. Compared to pristine cadmium sulfide nanocrystals (quantum efficiency ≅ 0.1%), the surface-passivated CdS nanoparticles showed significantly enhanced luminescence properties (quantum efficiency ≅ 20%). The surface passivation by H(2)O(2) injection was characterized using X-ray photoelectron spectroscopy, X-ray diffraction, and time-resolved PL. The photoluminescence enhancement is due to the two-order increase in the radiative recombination rate by the sulfate passivation layer. Springer 2012-12-12 /pmc/articles/PMC3570443/ /pubmed/23234569 http://dx.doi.org/10.1186/1556-276X-7-672 Text en Copyright ©2012 Lee et al.; licensee Springer. http://creativecommons.org/licenses/by/2.0 This is an Open Access article distributed under the terms of the Creative Commons Attribution License (http://creativecommons.org/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. |
spellingShingle | Nano Express Lee, Woojin Kim, Hoechang Jung, Dae-Ryong Kim, Jongmin Nahm, Changwoo Lee, Junhee Kang, Suji Lee, Byungho Park, Byungwoo An effective oxidation approach for luminescence enhancement in CdS quantum dots by H(2)O(2) |
title | An effective oxidation approach for luminescence enhancement in CdS quantum dots by H(2)O(2) |
title_full | An effective oxidation approach for luminescence enhancement in CdS quantum dots by H(2)O(2) |
title_fullStr | An effective oxidation approach for luminescence enhancement in CdS quantum dots by H(2)O(2) |
title_full_unstemmed | An effective oxidation approach for luminescence enhancement in CdS quantum dots by H(2)O(2) |
title_short | An effective oxidation approach for luminescence enhancement in CdS quantum dots by H(2)O(2) |
title_sort | effective oxidation approach for luminescence enhancement in cds quantum dots by h(2)o(2) |
topic | Nano Express |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3570443/ https://www.ncbi.nlm.nih.gov/pubmed/23234569 http://dx.doi.org/10.1186/1556-276X-7-672 |
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