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Photo- and electroluminescent properties europium complexes using bistriazole ligands

Luminescent properties of two heteroleptic dibenzoylmethanate europium(III) complexes with 1,3-bis(5-pyridin-2-yl-1,2,4-triazol-3-yl)propane (H(2)L(1)) and 1,4-bis(5-pyridin-2-yl-1,2,4-triazol-3-yl)butane (H(2)L(2)) as ancillary ligands are described. The two double-layer-type electroluminescent cel...

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Detalles Bibliográficos
Autores principales: Gusev, Alexey N., Shul’gin, Victor F., Nishimenko, Galina, Hasegawa, Miki, Linert, Wolfgang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Elsevier Sequoia] 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3584924/
https://www.ncbi.nlm.nih.gov/pubmed/23459422
http://dx.doi.org/10.1016/j.synthmet.2012.12.020
Descripción
Sumario:Luminescent properties of two heteroleptic dibenzoylmethanate europium(III) complexes with 1,3-bis(5-pyridin-2-yl-1,2,4-triazol-3-yl)propane (H(2)L(1)) and 1,4-bis(5-pyridin-2-yl-1,2,4-triazol-3-yl)butane (H(2)L(2)) as ancillary ligands are described. The two double-layer-type electroluminescent cells with the structures: (1) ITO/NPB(40 nm)/Eu(DBM)(2)HL(1) (40 nm)/LiF (1 nm)/Al (100 nm) and (2) ITO/NPB(40 nm)/Eu(DBM)(2)HL(2) (40 nm)/LiF (1 nm)/Al (100 nm) emit red light originating from the europium complexes. The device 2 gives the maximum brightness of 455 cd/m(2) at 19.2 V.