Cargando…
Evidence for Nonstatistical Dynamics in the Wolff Rearrangement of a Carbene
[Image: see text] Two (13)C-labeled isomers of the formal Diels−Alder adduct of acetylmethyloxirene to tetramethyl 1,2,4,5-benzenetetracarboxylate have been synthesized. Flash vacuum thermolysis of these adducts leads to various isotopic isomers of acetylmethylketene, the ratios of which have been d...
| Autores principales: | , , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2008
|
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3585475/ https://www.ncbi.nlm.nih.gov/pubmed/18700757 http://dx.doi.org/10.1021/ja803230a |