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Differentiation of Diastereoisomers of Protected 1,2-Diaminoalkylphosphonic Acids by EI Mass Spectrometry and Density Functional Theory

Electron ionization mass spectrometry and density functional theory (DFT) calculations have been used to study the fragmentation of diastereoisomers of protected 1,2-diaminoalkylphosphonic acids. The loss of a diethoxyphosphoryl group and the elimination of diethyl phosphonate were found to be compe...

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Detalles Bibliográficos
Autores principales: Drabik, Ewelina, Krasiński, Grzegorz, Cypryk, Marek, Błaszczyk, Roman, Gajda, Tadeusz, Sochacki, Marek
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Springer-Verlag 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3586168/
https://www.ncbi.nlm.nih.gov/pubmed/23393058
http://dx.doi.org/10.1007/s13361-012-0556-y

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