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Oxidative quenching within photosensitizer–acceptor dyads based on bis(bidentate) phosphine-connected osmium(II) bipyridyl light absorbers and reactive metal sites
For the first time oxidative quenching of OsP(2)N(4) chromophores by reactive Pt(II) or Pd(II) sites containing cis, trans, cis-1,2,3,4-tetrakis(diphenylphosphino)cyclobutane (dppcb) is directly observed despite the presence of a saturated cyclobutane backbone “bridge”. This dramatic effect is measu...
Autores principales: | Eller, Sylvia, Trettenbrein, Barbara, Oberhuber, Dennis, Strabler, Christof, Gutmann, Rene, van der Veer, Wytze E., Ruetz, Markus, Kopacka, Holger, Obendorf, Dagmar, Brüggeller, Peter |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Elsevier
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3587338/ https://www.ncbi.nlm.nih.gov/pubmed/23471298 http://dx.doi.org/10.1016/j.inoche.2012.06.001 |
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