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2-Hy­droxy-4-(prop-2-yn­yloxy)benz­alde­hyde

The asymmetric unit of the title compound, C(10)H(8)O(3), contains two independent mol­ecules, both of which are almost planar (r.m.s deviations for all non-H atoms of 0.044 and 0.053 Å). The dihedral angles between the benzene ring and the prop-1-yne group are 3.47 (1) and 3.07 (1)° in the two mol­...

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Detalles Bibliográficos
Autores principales: Selvarani, V., Neelakantan, M.A., Silambarasan, V., Velmurugan, D.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588223/
https://www.ncbi.nlm.nih.gov/pubmed/23476445
http://dx.doi.org/10.1107/S1600536812049598
Descripción
Sumario:The asymmetric unit of the title compound, C(10)H(8)O(3), contains two independent mol­ecules, both of which are almost planar (r.m.s deviations for all non-H atoms of 0.044 and 0.053 Å). The dihedral angles between the benzene ring and the prop-1-yne group are 3.47 (1) and 3.07 (1)° in the two mol­ecules, and the prop-1-yne groups adopt extended conformations. In each mol­ecule, an intra­molecular O—H⋯O hydrogen bond involving the OH and aldehyde substituents forms an S(6) ring. In the crystal, mol­ecules are linked into cyclic centrosymmetric dimers via C—H⋯O hydrogen bonds, generating R (2) (2)(14) ring motifs. The crystal structure is further stabilized by aromatic π–π stacking inter­actions between the benzene rings [centroid–centroid distances = 3.813 (2) and 3.843 (2) Å]