(E)-2,4,6-Trimethyl-N-[(1H-pyrrol-2-yl)methyl­idene]aniline

The title compound, C(14)H(16)N(2), is a pyrrole-2-carbaldimine ligand that shows an E conformation at the imine double bond. The dihedral angle between the rings is 78.3 (1)°. In the crystal, pairs of mol­ecules form centrosymmetric dimers [graph-set descriptor is presumably R (2) (2)(10)] via N—H⋯...

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Detalles Bibliográficos
Autor principal: Imhof, Wolfgang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588225/
https://www.ncbi.nlm.nih.gov/pubmed/23476376
http://dx.doi.org/10.1107/S160053681205057X
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author Imhof, Wolfgang
author_facet Imhof, Wolfgang
author_sort Imhof, Wolfgang
collection PubMed
description The title compound, C(14)H(16)N(2), is a pyrrole-2-carbaldimine ligand that shows an E conformation at the imine double bond. The dihedral angle between the rings is 78.3 (1)°. In the crystal, pairs of mol­ecules form centrosymmetric dimers [graph-set descriptor is presumably R (2) (2)(10)] via N—H⋯N hydrogen bonds between the pyrrole N—H group and the imine N atom of a neighbouring mol­ecule.
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spelling pubmed-35882252013-03-08 (E)-2,4,6-Trimethyl-N-[(1H-pyrrol-2-yl)methyl­idene]aniline Imhof, Wolfgang Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(14)H(16)N(2), is a pyrrole-2-carbaldimine ligand that shows an E conformation at the imine double bond. The dihedral angle between the rings is 78.3 (1)°. In the crystal, pairs of mol­ecules form centrosymmetric dimers [graph-set descriptor is presumably R (2) (2)(10)] via N—H⋯N hydrogen bonds between the pyrrole N—H group and the imine N atom of a neighbouring mol­ecule. International Union of Crystallography 2012-12-19 /pmc/articles/PMC3588225/ /pubmed/23476376 http://dx.doi.org/10.1107/S160053681205057X Text en © Wolfgang Imhof 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Imhof, Wolfgang
(E)-2,4,6-Trimethyl-N-[(1H-pyrrol-2-yl)methyl­idene]aniline
title (E)-2,4,6-Trimethyl-N-[(1H-pyrrol-2-yl)methyl­idene]aniline
title_full (E)-2,4,6-Trimethyl-N-[(1H-pyrrol-2-yl)methyl­idene]aniline
title_fullStr (E)-2,4,6-Trimethyl-N-[(1H-pyrrol-2-yl)methyl­idene]aniline
title_full_unstemmed (E)-2,4,6-Trimethyl-N-[(1H-pyrrol-2-yl)methyl­idene]aniline
title_short (E)-2,4,6-Trimethyl-N-[(1H-pyrrol-2-yl)methyl­idene]aniline
title_sort (e)-2,4,6-trimethyl-n-[(1h-pyrrol-2-yl)methyl­idene]aniline
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588225/
https://www.ncbi.nlm.nih.gov/pubmed/23476376
http://dx.doi.org/10.1107/S160053681205057X
work_keys_str_mv AT imhofwolfgang e246trimethyln1hpyrrol2ylmethylideneaniline

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