rac-(S,S)-Bis(1-ferrocenylbut-3-en­yl) ether

The title complex, [Fe(2)(C(5)H(5))(2)(C(18)H(20)O)], formed by dehydration of 1-ferrocenylbut-3-en-1-ol, crystallizes as a racemic compound. The central C—O—C fragment, in which the C atoms are the chiral centers, is characterized by an angle of 116.26 (10)° at the O atom. One ferrocene group shows...

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Detalles Bibliográficos
Autores principales: Xie, Hao-Jun, Zhao, Chun-Zheng, Sun, Jun, Chen, Si, Wang, Jian-Jun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588228/
https://www.ncbi.nlm.nih.gov/pubmed/23476318
http://dx.doi.org/10.1107/S1600536812048064
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author Xie, Hao-Jun
Zhao, Chun-Zheng
Sun, Jun
Chen, Si
Wang, Jian-Jun
author_facet Xie, Hao-Jun
Zhao, Chun-Zheng
Sun, Jun
Chen, Si
Wang, Jian-Jun
author_sort Xie, Hao-Jun
collection PubMed
description The title complex, [Fe(2)(C(5)H(5))(2)(C(18)H(20)O)], formed by dehydration of 1-ferrocenylbut-3-en-1-ol, crystallizes as a racemic compound. The central C—O—C fragment, in which the C atoms are the chiral centers, is characterized by an angle of 116.26 (10)° at the O atom. One ferrocene group shows a staggered conformation whereas the other shows an eclipsed conformation.
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spelling pubmed-35882282013-03-08 rac-(S,S)-Bis(1-ferrocenylbut-3-en­yl) ether Xie, Hao-Jun Zhao, Chun-Zheng Sun, Jun Chen, Si Wang, Jian-Jun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [Fe(2)(C(5)H(5))(2)(C(18)H(20)O)], formed by dehydration of 1-ferrocenylbut-3-en-1-ol, crystallizes as a racemic compound. The central C—O—C fragment, in which the C atoms are the chiral centers, is characterized by an angle of 116.26 (10)° at the O atom. One ferrocene group shows a staggered conformation whereas the other shows an eclipsed conformation. International Union of Crystallography 2012-12-08 /pmc/articles/PMC3588228/ /pubmed/23476318 http://dx.doi.org/10.1107/S1600536812048064 Text en © Xie et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Xie, Hao-Jun
Zhao, Chun-Zheng
Sun, Jun
Chen, Si
Wang, Jian-Jun
rac-(S,S)-Bis(1-ferrocenylbut-3-en­yl) ether
title rac-(S,S)-Bis(1-ferrocenylbut-3-en­yl) ether
title_full rac-(S,S)-Bis(1-ferrocenylbut-3-en­yl) ether
title_fullStr rac-(S,S)-Bis(1-ferrocenylbut-3-en­yl) ether
title_full_unstemmed rac-(S,S)-Bis(1-ferrocenylbut-3-en­yl) ether
title_short rac-(S,S)-Bis(1-ferrocenylbut-3-en­yl) ether
title_sort rac-(s,s)-bis(1-ferrocenylbut-3-en­yl) ether
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588228/
https://www.ncbi.nlm.nih.gov/pubmed/23476318
http://dx.doi.org/10.1107/S1600536812048064
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