Cargando…

Bis[(1RS,2RS)-4,4′-(1-aza­niumyl-2-hy­droxy­ethane-1,2-di­yl)dipyridinium] tris­[tetra­chloridopalladate(II)]

The asymmetric unit of the title compound, (C(12)H(16)N(3)O)(2)[PdCl(4)](3), consists of a 4,4′-(1-aza­niumyl-2-hy­droxy­ethane-1,2-di­yl)dipyridinium dication and one and a half tetra­chloridopalladate(II) anions; the latter has inversion symmetry. In the cation, the pyridinium rings attached to th...

Descripción completa

Detalles Bibliográficos
Autores principales: Campos-Gaxiola, Jose J., Baez-Castro, Alberto, Cruz-Enriquez, Adriana, Hopfl, Herbert, Parra-Hake, Miguel
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588234/
https://www.ncbi.nlm.nih.gov/pubmed/23476356
http://dx.doi.org/10.1107/S1600536812050817
Descripción
Sumario:The asymmetric unit of the title compound, (C(12)H(16)N(3)O)(2)[PdCl(4)](3), consists of a 4,4′-(1-aza­niumyl-2-hy­droxy­ethane-1,2-di­yl)dipyridinium dication and one and a half tetra­chloridopalladate(II) anions; the latter has inversion symmetry. In the cation, the pyridinium rings attached to the central 1-aza­niumyl-2-hy­droxy­ethane fragment show an anti conformation, as indicated by the central C—C—C—C torsion angle of −178.1 (4)°, and they are inclined to one another by 25.7 (2)°. In the crystal, the cations and anions are linked through N—H⋯Cl and O—H⋯Cl hydrogen bonds. There are also π–π contacts [centroid–centroid distance = 3.788 (3) Å] and a number of C—H⋯O and C—H⋯Cl inter­actions are present, consolidating the formation of a three-dimensional structure.