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Bis[(1RS,2RS)-4,4′-(1-aza­niumyl-2-hy­droxy­ethane-1,2-di­yl)dipyridinium] tris­[tetra­chloridopalladate(II)]

The asymmetric unit of the title compound, (C(12)H(16)N(3)O)(2)[PdCl(4)](3), consists of a 4,4′-(1-aza­niumyl-2-hy­droxy­ethane-1,2-di­yl)dipyridinium dication and one and a half tetra­chloridopalladate(II) anions; the latter has inversion symmetry. In the cation, the pyridinium rings attached to th...

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Autores principales: Campos-Gaxiola, Jose J., Baez-Castro, Alberto, Cruz-Enriquez, Adriana, Hopfl, Herbert, Parra-Hake, Miguel
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588234/
https://www.ncbi.nlm.nih.gov/pubmed/23476356
http://dx.doi.org/10.1107/S1600536812050817
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author Campos-Gaxiola, Jose J.
Baez-Castro, Alberto
Cruz-Enriquez, Adriana
Hopfl, Herbert
Parra-Hake, Miguel
author_facet Campos-Gaxiola, Jose J.
Baez-Castro, Alberto
Cruz-Enriquez, Adriana
Hopfl, Herbert
Parra-Hake, Miguel
author_sort Campos-Gaxiola, Jose J.
collection PubMed
description The asymmetric unit of the title compound, (C(12)H(16)N(3)O)(2)[PdCl(4)](3), consists of a 4,4′-(1-aza­niumyl-2-hy­droxy­ethane-1,2-di­yl)dipyridinium dication and one and a half tetra­chloridopalladate(II) anions; the latter has inversion symmetry. In the cation, the pyridinium rings attached to the central 1-aza­niumyl-2-hy­droxy­ethane fragment show an anti conformation, as indicated by the central C—C—C—C torsion angle of −178.1 (4)°, and they are inclined to one another by 25.7 (2)°. In the crystal, the cations and anions are linked through N—H⋯Cl and O—H⋯Cl hydrogen bonds. There are also π–π contacts [centroid–centroid distance = 3.788 (3) Å] and a number of C—H⋯O and C—H⋯Cl inter­actions are present, consolidating the formation of a three-dimensional structure.
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spelling pubmed-35882342013-03-08 Bis[(1RS,2RS)-4,4′-(1-aza­niumyl-2-hy­droxy­ethane-1,2-di­yl)dipyridinium] tris­[tetra­chloridopalladate(II)] Campos-Gaxiola, Jose J. Baez-Castro, Alberto Cruz-Enriquez, Adriana Hopfl, Herbert Parra-Hake, Miguel Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, (C(12)H(16)N(3)O)(2)[PdCl(4)](3), consists of a 4,4′-(1-aza­niumyl-2-hy­droxy­ethane-1,2-di­yl)dipyridinium dication and one and a half tetra­chloridopalladate(II) anions; the latter has inversion symmetry. In the cation, the pyridinium rings attached to the central 1-aza­niumyl-2-hy­droxy­ethane fragment show an anti conformation, as indicated by the central C—C—C—C torsion angle of −178.1 (4)°, and they are inclined to one another by 25.7 (2)°. In the crystal, the cations and anions are linked through N—H⋯Cl and O—H⋯Cl hydrogen bonds. There are also π–π contacts [centroid–centroid distance = 3.788 (3) Å] and a number of C—H⋯O and C—H⋯Cl inter­actions are present, consolidating the formation of a three-dimensional structure. International Union of Crystallography 2012-12-22 /pmc/articles/PMC3588234/ /pubmed/23476356 http://dx.doi.org/10.1107/S1600536812050817 Text en © Campos-Gaxiola et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Campos-Gaxiola, Jose J.
Baez-Castro, Alberto
Cruz-Enriquez, Adriana
Hopfl, Herbert
Parra-Hake, Miguel
Bis[(1RS,2RS)-4,4′-(1-aza­niumyl-2-hy­droxy­ethane-1,2-di­yl)dipyridinium] tris­[tetra­chloridopalladate(II)]
title Bis[(1RS,2RS)-4,4′-(1-aza­niumyl-2-hy­droxy­ethane-1,2-di­yl)dipyridinium] tris­[tetra­chloridopalladate(II)]
title_full Bis[(1RS,2RS)-4,4′-(1-aza­niumyl-2-hy­droxy­ethane-1,2-di­yl)dipyridinium] tris­[tetra­chloridopalladate(II)]
title_fullStr Bis[(1RS,2RS)-4,4′-(1-aza­niumyl-2-hy­droxy­ethane-1,2-di­yl)dipyridinium] tris­[tetra­chloridopalladate(II)]
title_full_unstemmed Bis[(1RS,2RS)-4,4′-(1-aza­niumyl-2-hy­droxy­ethane-1,2-di­yl)dipyridinium] tris­[tetra­chloridopalladate(II)]
title_short Bis[(1RS,2RS)-4,4′-(1-aza­niumyl-2-hy­droxy­ethane-1,2-di­yl)dipyridinium] tris­[tetra­chloridopalladate(II)]
title_sort bis[(1rs,2rs)-4,4′-(1-aza­niumyl-2-hy­droxy­ethane-1,2-di­yl)dipyridinium] tris­[tetra­chloridopalladate(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588234/
https://www.ncbi.nlm.nih.gov/pubmed/23476356
http://dx.doi.org/10.1107/S1600536812050817
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