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Bis[(1RS,2RS)-4,4′-(1-azaniumyl-2-hydroxyethane-1,2-diyl)dipyridinium] tris[tetrachloridopalladate(II)]
The asymmetric unit of the title compound, (C(12)H(16)N(3)O)(2)[PdCl(4)](3), consists of a 4,4′-(1-azaniumyl-2-hydroxyethane-1,2-diyl)dipyridinium dication and one and a half tetrachloridopalladate(II) anions; the latter has inversion symmetry. In the cation, the pyridinium rings attached to th...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588234/ https://www.ncbi.nlm.nih.gov/pubmed/23476356 http://dx.doi.org/10.1107/S1600536812050817 |
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author | Campos-Gaxiola, Jose J. Baez-Castro, Alberto Cruz-Enriquez, Adriana Hopfl, Herbert Parra-Hake, Miguel |
author_facet | Campos-Gaxiola, Jose J. Baez-Castro, Alberto Cruz-Enriquez, Adriana Hopfl, Herbert Parra-Hake, Miguel |
author_sort | Campos-Gaxiola, Jose J. |
collection | PubMed |
description | The asymmetric unit of the title compound, (C(12)H(16)N(3)O)(2)[PdCl(4)](3), consists of a 4,4′-(1-azaniumyl-2-hydroxyethane-1,2-diyl)dipyridinium dication and one and a half tetrachloridopalladate(II) anions; the latter has inversion symmetry. In the cation, the pyridinium rings attached to the central 1-azaniumyl-2-hydroxyethane fragment show an anti conformation, as indicated by the central C—C—C—C torsion angle of −178.1 (4)°, and they are inclined to one another by 25.7 (2)°. In the crystal, the cations and anions are linked through N—H⋯Cl and O—H⋯Cl hydrogen bonds. There are also π–π contacts [centroid–centroid distance = 3.788 (3) Å] and a number of C—H⋯O and C—H⋯Cl interactions are present, consolidating the formation of a three-dimensional structure. |
format | Online Article Text |
id | pubmed-3588234 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-35882342013-03-08 Bis[(1RS,2RS)-4,4′-(1-azaniumyl-2-hydroxyethane-1,2-diyl)dipyridinium] tris[tetrachloridopalladate(II)] Campos-Gaxiola, Jose J. Baez-Castro, Alberto Cruz-Enriquez, Adriana Hopfl, Herbert Parra-Hake, Miguel Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, (C(12)H(16)N(3)O)(2)[PdCl(4)](3), consists of a 4,4′-(1-azaniumyl-2-hydroxyethane-1,2-diyl)dipyridinium dication and one and a half tetrachloridopalladate(II) anions; the latter has inversion symmetry. In the cation, the pyridinium rings attached to the central 1-azaniumyl-2-hydroxyethane fragment show an anti conformation, as indicated by the central C—C—C—C torsion angle of −178.1 (4)°, and they are inclined to one another by 25.7 (2)°. In the crystal, the cations and anions are linked through N—H⋯Cl and O—H⋯Cl hydrogen bonds. There are also π–π contacts [centroid–centroid distance = 3.788 (3) Å] and a number of C—H⋯O and C—H⋯Cl interactions are present, consolidating the formation of a three-dimensional structure. International Union of Crystallography 2012-12-22 /pmc/articles/PMC3588234/ /pubmed/23476356 http://dx.doi.org/10.1107/S1600536812050817 Text en © Campos-Gaxiola et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Campos-Gaxiola, Jose J. Baez-Castro, Alberto Cruz-Enriquez, Adriana Hopfl, Herbert Parra-Hake, Miguel Bis[(1RS,2RS)-4,4′-(1-azaniumyl-2-hydroxyethane-1,2-diyl)dipyridinium] tris[tetrachloridopalladate(II)] |
title | Bis[(1RS,2RS)-4,4′-(1-azaniumyl-2-hydroxyethane-1,2-diyl)dipyridinium] tris[tetrachloridopalladate(II)] |
title_full | Bis[(1RS,2RS)-4,4′-(1-azaniumyl-2-hydroxyethane-1,2-diyl)dipyridinium] tris[tetrachloridopalladate(II)] |
title_fullStr | Bis[(1RS,2RS)-4,4′-(1-azaniumyl-2-hydroxyethane-1,2-diyl)dipyridinium] tris[tetrachloridopalladate(II)] |
title_full_unstemmed | Bis[(1RS,2RS)-4,4′-(1-azaniumyl-2-hydroxyethane-1,2-diyl)dipyridinium] tris[tetrachloridopalladate(II)] |
title_short | Bis[(1RS,2RS)-4,4′-(1-azaniumyl-2-hydroxyethane-1,2-diyl)dipyridinium] tris[tetrachloridopalladate(II)] |
title_sort | bis[(1rs,2rs)-4,4′-(1-azaniumyl-2-hydroxyethane-1,2-diyl)dipyridinium] tris[tetrachloridopalladate(ii)] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588234/ https://www.ncbi.nlm.nih.gov/pubmed/23476356 http://dx.doi.org/10.1107/S1600536812050817 |
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