Dichlorido{N-[(5-methyl­thio­phen-2-yl)methyl­idene]-2-(pyridin-2-yl)ethanamine-κ(2) N,N′}palladium(II)

In the title compound, [PdCl(2)(C(13)H(14)N(2)S)], the Pd(II) ion is coordinated by two N atoms of the chelating bidentate ligand and two chloride anions, giving rise to a distorted square-planar geometry. The methyl-substituted thio­phene arm and the pyridine ring are connected to the metal cation...

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Detalles Bibliográficos
Autores principales: Radebe, Mduduzi P., Onani, Martin O., Motswainyana, William M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588236/
https://www.ncbi.nlm.nih.gov/pubmed/23476321
http://dx.doi.org/10.1107/S1600536812049240
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author Radebe, Mduduzi P.
Onani, Martin O.
Motswainyana, William M.
author_facet Radebe, Mduduzi P.
Onani, Martin O.
Motswainyana, William M.
author_sort Radebe, Mduduzi P.
collection PubMed
description In the title compound, [PdCl(2)(C(13)H(14)N(2)S)], the Pd(II) ion is coordinated by two N atoms of the chelating bidentate ligand and two chloride anions, giving rise to a distorted square-planar geometry. The methyl-substituted thio­phene arm and the pyridine ring are connected to the metal cation through N atoms to form a six-membered chelate ring with a boat conformation, making the complex stable.
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spelling pubmed-35882362013-03-08 Dichlorido{N-[(5-methyl­thio­phen-2-yl)methyl­idene]-2-(pyridin-2-yl)ethanamine-κ(2) N,N′}palladium(II) Radebe, Mduduzi P. Onani, Martin O. Motswainyana, William M. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [PdCl(2)(C(13)H(14)N(2)S)], the Pd(II) ion is coordinated by two N atoms of the chelating bidentate ligand and two chloride anions, giving rise to a distorted square-planar geometry. The methyl-substituted thio­phene arm and the pyridine ring are connected to the metal cation through N atoms to form a six-membered chelate ring with a boat conformation, making the complex stable. International Union of Crystallography 2012-12-08 /pmc/articles/PMC3588236/ /pubmed/23476321 http://dx.doi.org/10.1107/S1600536812049240 Text en © Radebe et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Radebe, Mduduzi P.
Onani, Martin O.
Motswainyana, William M.
Dichlorido{N-[(5-methyl­thio­phen-2-yl)methyl­idene]-2-(pyridin-2-yl)ethanamine-κ(2) N,N′}palladium(II)
title Dichlorido{N-[(5-methyl­thio­phen-2-yl)methyl­idene]-2-(pyridin-2-yl)ethanamine-κ(2) N,N′}palladium(II)
title_full Dichlorido{N-[(5-methyl­thio­phen-2-yl)methyl­idene]-2-(pyridin-2-yl)ethanamine-κ(2) N,N′}palladium(II)
title_fullStr Dichlorido{N-[(5-methyl­thio­phen-2-yl)methyl­idene]-2-(pyridin-2-yl)ethanamine-κ(2) N,N′}palladium(II)
title_full_unstemmed Dichlorido{N-[(5-methyl­thio­phen-2-yl)methyl­idene]-2-(pyridin-2-yl)ethanamine-κ(2) N,N′}palladium(II)
title_short Dichlorido{N-[(5-methyl­thio­phen-2-yl)methyl­idene]-2-(pyridin-2-yl)ethanamine-κ(2) N,N′}palladium(II)
title_sort dichlorido{n-[(5-methyl­thio­phen-2-yl)methyl­idene]-2-(pyridin-2-yl)ethanamine-κ(2) n,n′}palladium(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588236/
https://www.ncbi.nlm.nih.gov/pubmed/23476321
http://dx.doi.org/10.1107/S1600536812049240
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AT motswainyanawilliamm dichloridon5methylthiophen2ylmethylidene2pyridin2ylethanaminek2nnpalladiumii

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