Cargando…

[2-(3,4-Dimethyl­benzo­yl)phen­yl](4-meth­oxy­phen­yl)methanone

The title mol­ecule, C(23)H(20)O(3), is disordered with a 180° rotation about an axis normal to the length of the mol­ecule, with the major and minor components in a 0.545 (5):0.455 (5) ratio. In the major component, the central benzene ring forms dihedral angles of 72.34 (3) and 69.46 (3)° with the...

Descripción completa

Detalles Bibliográficos
Autores principales: Jagadeesan, G., Sethusankar, K., Sivasakthikumaran, R., Mohanakrishnan, Arasambattu K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588237/
https://www.ncbi.nlm.nih.gov/pubmed/23476413
http://dx.doi.org/10.1107/S1600536812047654
_version_ 1782261519742926848
author Jagadeesan, G.
Sethusankar, K.
Sivasakthikumaran, R.
Mohanakrishnan, Arasambattu K.
author_facet Jagadeesan, G.
Sethusankar, K.
Sivasakthikumaran, R.
Mohanakrishnan, Arasambattu K.
author_sort Jagadeesan, G.
collection PubMed
description The title mol­ecule, C(23)H(20)O(3), is disordered with a 180° rotation about an axis normal to the length of the mol­ecule, with the major and minor components in a 0.545 (5):0.455 (5) ratio. In the major component, the central benzene ring forms dihedral angles of 72.34 (3) and 69.46 (3)° with the dimethyl-substituted and meth­oxy-substituted benzene rings, respectively. Moreover, the central benzene ring forms dihedral angles of 50.86 (5) and 58.43 (4)° with the mean planes of the ketone groups. In the minor component, the corresponding dihedral angles between the benzene rings are 71.36 (4) and 67.94 (4)° and the dihedral angles between the benzene ring and the ketone groups are 56.44 (9) and 55.51 (8)°. In the crystal, C—H⋯O inter­actions generate a C(9) chain along the a-axis direction.
format Online
Article
Text
id pubmed-3588237
institution National Center for Biotechnology Information
language English
publishDate 2012
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-35882372013-03-08 [2-(3,4-Dimethyl­benzo­yl)phen­yl](4-meth­oxy­phen­yl)methanone Jagadeesan, G. Sethusankar, K. Sivasakthikumaran, R. Mohanakrishnan, Arasambattu K. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title mol­ecule, C(23)H(20)O(3), is disordered with a 180° rotation about an axis normal to the length of the mol­ecule, with the major and minor components in a 0.545 (5):0.455 (5) ratio. In the major component, the central benzene ring forms dihedral angles of 72.34 (3) and 69.46 (3)° with the dimethyl-substituted and meth­oxy-substituted benzene rings, respectively. Moreover, the central benzene ring forms dihedral angles of 50.86 (5) and 58.43 (4)° with the mean planes of the ketone groups. In the minor component, the corresponding dihedral angles between the benzene rings are 71.36 (4) and 67.94 (4)° and the dihedral angles between the benzene ring and the ketone groups are 56.44 (9) and 55.51 (8)°. In the crystal, C—H⋯O inter­actions generate a C(9) chain along the a-axis direction. International Union of Crystallography 2012-12-05 /pmc/articles/PMC3588237/ /pubmed/23476413 http://dx.doi.org/10.1107/S1600536812047654 Text en © Jagadeesan et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Jagadeesan, G.
Sethusankar, K.
Sivasakthikumaran, R.
Mohanakrishnan, Arasambattu K.
[2-(3,4-Dimethyl­benzo­yl)phen­yl](4-meth­oxy­phen­yl)methanone
title [2-(3,4-Dimethyl­benzo­yl)phen­yl](4-meth­oxy­phen­yl)methanone
title_full [2-(3,4-Dimethyl­benzo­yl)phen­yl](4-meth­oxy­phen­yl)methanone
title_fullStr [2-(3,4-Dimethyl­benzo­yl)phen­yl](4-meth­oxy­phen­yl)methanone
title_full_unstemmed [2-(3,4-Dimethyl­benzo­yl)phen­yl](4-meth­oxy­phen­yl)methanone
title_short [2-(3,4-Dimethyl­benzo­yl)phen­yl](4-meth­oxy­phen­yl)methanone
title_sort [2-(3,4-dimethyl­benzo­yl)phen­yl](4-meth­oxy­phen­yl)methanone
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588237/
https://www.ncbi.nlm.nih.gov/pubmed/23476413
http://dx.doi.org/10.1107/S1600536812047654
work_keys_str_mv AT jagadeesang 234dimethylbenzoylphenyl4methoxyphenylmethanone
AT sethusankark 234dimethylbenzoylphenyl4methoxyphenylmethanone
AT sivasakthikumaranr 234dimethylbenzoylphenyl4methoxyphenylmethanone
AT mohanakrishnanarasambattuk 234dimethylbenzoylphenyl4methoxyphenylmethanone