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[2-(3,4-Dimethylbenzoyl)phenyl](4-methoxyphenyl)methanone
The title molecule, C(23)H(20)O(3), is disordered with a 180° rotation about an axis normal to the length of the molecule, with the major and minor components in a 0.545 (5):0.455 (5) ratio. In the major component, the central benzene ring forms dihedral angles of 72.34 (3) and 69.46 (3)° with the...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588237/ https://www.ncbi.nlm.nih.gov/pubmed/23476413 http://dx.doi.org/10.1107/S1600536812047654 |
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author | Jagadeesan, G. Sethusankar, K. Sivasakthikumaran, R. Mohanakrishnan, Arasambattu K. |
author_facet | Jagadeesan, G. Sethusankar, K. Sivasakthikumaran, R. Mohanakrishnan, Arasambattu K. |
author_sort | Jagadeesan, G. |
collection | PubMed |
description | The title molecule, C(23)H(20)O(3), is disordered with a 180° rotation about an axis normal to the length of the molecule, with the major and minor components in a 0.545 (5):0.455 (5) ratio. In the major component, the central benzene ring forms dihedral angles of 72.34 (3) and 69.46 (3)° with the dimethyl-substituted and methoxy-substituted benzene rings, respectively. Moreover, the central benzene ring forms dihedral angles of 50.86 (5) and 58.43 (4)° with the mean planes of the ketone groups. In the minor component, the corresponding dihedral angles between the benzene rings are 71.36 (4) and 67.94 (4)° and the dihedral angles between the benzene ring and the ketone groups are 56.44 (9) and 55.51 (8)°. In the crystal, C—H⋯O interactions generate a C(9) chain along the a-axis direction. |
format | Online Article Text |
id | pubmed-3588237 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-35882372013-03-08 [2-(3,4-Dimethylbenzoyl)phenyl](4-methoxyphenyl)methanone Jagadeesan, G. Sethusankar, K. Sivasakthikumaran, R. Mohanakrishnan, Arasambattu K. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title molecule, C(23)H(20)O(3), is disordered with a 180° rotation about an axis normal to the length of the molecule, with the major and minor components in a 0.545 (5):0.455 (5) ratio. In the major component, the central benzene ring forms dihedral angles of 72.34 (3) and 69.46 (3)° with the dimethyl-substituted and methoxy-substituted benzene rings, respectively. Moreover, the central benzene ring forms dihedral angles of 50.86 (5) and 58.43 (4)° with the mean planes of the ketone groups. In the minor component, the corresponding dihedral angles between the benzene rings are 71.36 (4) and 67.94 (4)° and the dihedral angles between the benzene ring and the ketone groups are 56.44 (9) and 55.51 (8)°. In the crystal, C—H⋯O interactions generate a C(9) chain along the a-axis direction. International Union of Crystallography 2012-12-05 /pmc/articles/PMC3588237/ /pubmed/23476413 http://dx.doi.org/10.1107/S1600536812047654 Text en © Jagadeesan et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Jagadeesan, G. Sethusankar, K. Sivasakthikumaran, R. Mohanakrishnan, Arasambattu K. [2-(3,4-Dimethylbenzoyl)phenyl](4-methoxyphenyl)methanone |
title | [2-(3,4-Dimethylbenzoyl)phenyl](4-methoxyphenyl)methanone |
title_full | [2-(3,4-Dimethylbenzoyl)phenyl](4-methoxyphenyl)methanone |
title_fullStr | [2-(3,4-Dimethylbenzoyl)phenyl](4-methoxyphenyl)methanone |
title_full_unstemmed | [2-(3,4-Dimethylbenzoyl)phenyl](4-methoxyphenyl)methanone |
title_short | [2-(3,4-Dimethylbenzoyl)phenyl](4-methoxyphenyl)methanone |
title_sort | [2-(3,4-dimethylbenzoyl)phenyl](4-methoxyphenyl)methanone |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588237/ https://www.ncbi.nlm.nih.gov/pubmed/23476413 http://dx.doi.org/10.1107/S1600536812047654 |
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