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μ-Azido-κ(2) N (1):N (1)-μ-chlorido-bis­[(2-chloro-3-dimethyl­amino-1-phenyl­prop-1-en-1-yl-κ(2) C (1),N)palladium(II)] chloro­form monosolvate

In the binuclear title complex, [Pd(2)(C(11)H(13)ClN)(2)Cl(N(3))]·CHCl(3), each Pd(II) atom has a slightly distorted square-planar geometry being coordinated by a C and an N atom of the 2-chloro-3-dimethyl­amino-1-phenyl­propyl ligand, a bridging Cl atom and an N atom of a bridging end-on azide grou...

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Detalles Bibliográficos
Autores principales: Mafud, Ana C., Oliviera, Milene A. R., Gambardella, Maria T. P.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588240/
https://www.ncbi.nlm.nih.gov/pubmed/23476317
http://dx.doi.org/10.1107/S1600536812047927
Descripción
Sumario:In the binuclear title complex, [Pd(2)(C(11)H(13)ClN)(2)Cl(N(3))]·CHCl(3), each Pd(II) atom has a slightly distorted square-planar geometry being coordinated by a C and an N atom of the 2-chloro-3-dimethyl­amino-1-phenyl­propyl ligand, a bridging Cl atom and an N atom of a bridging end-on azide group. There is a short intra­molecular C—H⋯Cl contact in the complex mol­ecule. In the crystal, the chloro­form solvent mol­ecule is linked to the complex via a C—H⋯π inter­action.