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μ-Azido-κ(2) N (1):N (1)-μ-chlorido-bis[(2-chloro-3-dimethylamino-1-phenylprop-1-en-1-yl-κ(2) C (1),N)palladium(II)] chloroform monosolvate
In the binuclear title complex, [Pd(2)(C(11)H(13)ClN)(2)Cl(N(3))]·CHCl(3), each Pd(II) atom has a slightly distorted square-planar geometry being coordinated by a C and an N atom of the 2-chloro-3-dimethylamino-1-phenylpropyl ligand, a bridging Cl atom and an N atom of a bridging end-on azide grou...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588240/ https://www.ncbi.nlm.nih.gov/pubmed/23476317 http://dx.doi.org/10.1107/S1600536812047927 |
Sumario: | In the binuclear title complex, [Pd(2)(C(11)H(13)ClN)(2)Cl(N(3))]·CHCl(3), each Pd(II) atom has a slightly distorted square-planar geometry being coordinated by a C and an N atom of the 2-chloro-3-dimethylamino-1-phenylpropyl ligand, a bridging Cl atom and an N atom of a bridging end-on azide group. There is a short intramolecular C—H⋯Cl contact in the complex molecule. In the crystal, the chloroform solvent molecule is linked to the complex via a C—H⋯π interaction. |
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