Tris[4-(dimethyl­amino)­pyridinium] hexa­kis­(thio­cyanato-κN)ferrate(III) monohydrate

In the title compound, (C(7)H(11)N(2))(3)[Fe(NCS)(6)]·H(2)O, the Fe(III) cation is coordinated by six terminal N-bonded thio­cyanate anions into a discrete threefold negatively charged complex. Charge balance is achieved by three protonated 4-(dimethyl­amino)­pyridine cations. The asymmetric unit co...

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Detalles Bibliográficos
Autores principales: Wöhlert, Susanne, Jess, Inke, Näther, Christian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588242/
https://www.ncbi.nlm.nih.gov/pubmed/23476331
http://dx.doi.org/10.1107/S1600536812049574
Descripción
Sumario:In the title compound, (C(7)H(11)N(2))(3)[Fe(NCS)(6)]·H(2)O, the Fe(III) cation is coordinated by six terminal N-bonded thio­cyanate anions into a discrete threefold negatively charged complex. Charge balance is achieved by three protonated 4-(dimethyl­amino)­pyridine cations. The asymmetric unit consists of one Fe(III) cation, six thio­cyanate anions, three 4-(dimethyl­amino)­pyridinium cations and one water mol­ecule, all of them located in general positions.

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