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(E)-16-(4-Chloro­benzyl­idene)estrone

In the title compound, C(25)H(25)ClO(2), the C ring adopts a chair conformation, while the B ring approximates a half-chair conformation. The five-membered ring D has a twist con­form­ation on the C—C bond fused with the C ring. Aromatic rings A and E are not coplanar, as evidenced by the dihedral a...

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Detalles Bibliográficos
Autores principales: Suresh, J., Thenmozhi, H., Jeyachandran, Veerappan, Kumar, R. Ranjith, Lakshman, P. L. Nilantha
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588250/
https://www.ncbi.nlm.nih.gov/pubmed/23476374
http://dx.doi.org/10.1107/S1600536812050349
Descripción
Sumario:In the title compound, C(25)H(25)ClO(2), the C ring adopts a chair conformation, while the B ring approximates a half-chair conformation. The five-membered ring D has a twist con­form­ation on the C—C bond fused with the C ring. Aromatic rings A and E are not coplanar, as evidenced by the dihedral angle of 7.51 (1)°. In the crystal, O—H⋯O hydrogen bonds form a double chain along the ab plane inter­connected by C—H⋯O inter­actions.