Benzyl­triphenyl­phospho­nium dichlorido­triphenyl­stannate(IV)

The crystal structure of the title salt, (C(25)H(22)P)[Sn(C(6)H(5))(3)Cl(2)] or (PhCH(2)PPh(3))[SnPh(3)Cl(2)], consists of [PhCH(2)PPh(3)](+) cations and [SnPh(3)Cl(2)](−) anions in which the Sn(IV) atom is linked to two Cl atoms and three phenyl groups in a trigonal–bipyramidal geometry, with the C...

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Detalles Bibliográficos
Autores principales: Traore, Bocar, Boye, Mouhamadou Sembene, Sidibe, Mamadou, Diop, Libasse, Guionneau, Philippe
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588253/
https://www.ncbi.nlm.nih.gov/pubmed/23476339
http://dx.doi.org/10.1107/S1600536812049689
Descripción
Sumario:The crystal structure of the title salt, (C(25)H(22)P)[Sn(C(6)H(5))(3)Cl(2)] or (PhCH(2)PPh(3))[SnPh(3)Cl(2)], consists of [PhCH(2)PPh(3)](+) cations and [SnPh(3)Cl(2)](−) anions in which the Sn(IV) atom is linked to two Cl atoms and three phenyl groups in a trigonal–bipyramidal geometry, with the Cl atoms in trans positions. The cation adopts a tetra­hedral geometry. In the crystal, the cations and the anions are connected by C—H⋯Cl hydrogen bonds, leading to an infinite chain propagating along the c direction.

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