Benzyl­triphenyl­phospho­nium dichlorido­triphenyl­stannate(IV)

The crystal structure of the title salt, (C(25)H(22)P)[Sn(C(6)H(5))(3)Cl(2)] or (PhCH(2)PPh(3))[SnPh(3)Cl(2)], consists of [PhCH(2)PPh(3)](+) cations and [SnPh(3)Cl(2)](−) anions in which the Sn(IV) atom is linked to two Cl atoms and three phenyl groups in a trigonal–bipyramidal geometry, with the C...

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Autores principales: Traore, Bocar, Boye, Mouhamadou Sembene, Sidibe, Mamadou, Diop, Libasse, Guionneau, Philippe
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588253/
https://www.ncbi.nlm.nih.gov/pubmed/23476339
http://dx.doi.org/10.1107/S1600536812049689
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author Traore, Bocar
Boye, Mouhamadou Sembene
Sidibe, Mamadou
Diop, Libasse
Guionneau, Philippe
author_facet Traore, Bocar
Boye, Mouhamadou Sembene
Sidibe, Mamadou
Diop, Libasse
Guionneau, Philippe
author_sort Traore, Bocar
collection PubMed
description The crystal structure of the title salt, (C(25)H(22)P)[Sn(C(6)H(5))(3)Cl(2)] or (PhCH(2)PPh(3))[SnPh(3)Cl(2)], consists of [PhCH(2)PPh(3)](+) cations and [SnPh(3)Cl(2)](−) anions in which the Sn(IV) atom is linked to two Cl atoms and three phenyl groups in a trigonal–bipyramidal geometry, with the Cl atoms in trans positions. The cation adopts a tetra­hedral geometry. In the crystal, the cations and the anions are connected by C—H⋯Cl hydrogen bonds, leading to an infinite chain propagating along the c direction.
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spelling pubmed-35882532013-03-08 Benzyl­triphenyl­phospho­nium dichlorido­triphenyl­stannate(IV) Traore, Bocar Boye, Mouhamadou Sembene Sidibe, Mamadou Diop, Libasse Guionneau, Philippe Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The crystal structure of the title salt, (C(25)H(22)P)[Sn(C(6)H(5))(3)Cl(2)] or (PhCH(2)PPh(3))[SnPh(3)Cl(2)], consists of [PhCH(2)PPh(3)](+) cations and [SnPh(3)Cl(2)](−) anions in which the Sn(IV) atom is linked to two Cl atoms and three phenyl groups in a trigonal–bipyramidal geometry, with the Cl atoms in trans positions. The cation adopts a tetra­hedral geometry. In the crystal, the cations and the anions are connected by C—H⋯Cl hydrogen bonds, leading to an infinite chain propagating along the c direction. International Union of Crystallography 2012-12-12 /pmc/articles/PMC3588253/ /pubmed/23476339 http://dx.doi.org/10.1107/S1600536812049689 Text en © Traore et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Traore, Bocar
Boye, Mouhamadou Sembene
Sidibe, Mamadou
Diop, Libasse
Guionneau, Philippe
Benzyl­triphenyl­phospho­nium dichlorido­triphenyl­stannate(IV)
title Benzyl­triphenyl­phospho­nium dichlorido­triphenyl­stannate(IV)
title_full Benzyl­triphenyl­phospho­nium dichlorido­triphenyl­stannate(IV)
title_fullStr Benzyl­triphenyl­phospho­nium dichlorido­triphenyl­stannate(IV)
title_full_unstemmed Benzyl­triphenyl­phospho­nium dichlorido­triphenyl­stannate(IV)
title_short Benzyl­triphenyl­phospho­nium dichlorido­triphenyl­stannate(IV)
title_sort benzyl­triphenyl­phospho­nium dichlorido­triphenyl­stannate(iv)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588253/
https://www.ncbi.nlm.nih.gov/pubmed/23476339
http://dx.doi.org/10.1107/S1600536812049689
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