2-(4-Meth­oxy­phen­yl)-1-pentyl-4,5-di­phenyl-1H-imidazole

The title compound, C(27)H(28)N(2)O, is a lophine (2,4,5-triphenyl-1H-imidazole) derivative with an n-pentyl chain on the amine N atom and a 4-meth­oxy substituent on the benzene ring. The two phenyl and meth­oxy­benzene rings are inclined to the imidazole ring at angles of 25.32 (7), 76.79 (5) and...

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Autores principales: Simpson, Jim, Mohamed, Shaaban K., Marzouk, Adel A., Talybov, Avtandil H., Abdelhamid, Antar A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588259/
https://www.ncbi.nlm.nih.gov/pubmed/23476433
http://dx.doi.org/10.1107/S1600536812049100
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author Simpson, Jim
Mohamed, Shaaban K.
Marzouk, Adel A.
Talybov, Avtandil H.
Abdelhamid, Antar A.
author_facet Simpson, Jim
Mohamed, Shaaban K.
Marzouk, Adel A.
Talybov, Avtandil H.
Abdelhamid, Antar A.
author_sort Simpson, Jim
collection PubMed
description The title compound, C(27)H(28)N(2)O, is a lophine (2,4,5-triphenyl-1H-imidazole) derivative with an n-pentyl chain on the amine N atom and a 4-meth­oxy substituent on the benzene ring. The two phenyl and meth­oxy­benzene rings are inclined to the imidazole ring at angles of 25.32 (7), 76.79 (5) and 35.42 (7)°, respectively, while the meth­oxy substituent lies close to the plane of its benzene ring, with a maximum deviation of 0.126 (3) Å for the meth­oxy C atom. In the crystal, inversion dimers linked by pairs of C—H⋯O hydrogen bonds generate R (2) (2)(22) loops. These dimers are stacked along the a-axis direction.
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spelling pubmed-35882592013-03-08 2-(4-Meth­oxy­phen­yl)-1-pentyl-4,5-di­phenyl-1H-imidazole Simpson, Jim Mohamed, Shaaban K. Marzouk, Adel A. Talybov, Avtandil H. Abdelhamid, Antar A. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(27)H(28)N(2)O, is a lophine (2,4,5-triphenyl-1H-imidazole) derivative with an n-pentyl chain on the amine N atom and a 4-meth­oxy substituent on the benzene ring. The two phenyl and meth­oxy­benzene rings are inclined to the imidazole ring at angles of 25.32 (7), 76.79 (5) and 35.42 (7)°, respectively, while the meth­oxy substituent lies close to the plane of its benzene ring, with a maximum deviation of 0.126 (3) Å for the meth­oxy C atom. In the crystal, inversion dimers linked by pairs of C—H⋯O hydrogen bonds generate R (2) (2)(22) loops. These dimers are stacked along the a-axis direction. International Union of Crystallography 2012-12-05 /pmc/articles/PMC3588259/ /pubmed/23476433 http://dx.doi.org/10.1107/S1600536812049100 Text en © Simpson et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Simpson, Jim
Mohamed, Shaaban K.
Marzouk, Adel A.
Talybov, Avtandil H.
Abdelhamid, Antar A.
2-(4-Meth­oxy­phen­yl)-1-pentyl-4,5-di­phenyl-1H-imidazole
title 2-(4-Meth­oxy­phen­yl)-1-pentyl-4,5-di­phenyl-1H-imidazole
title_full 2-(4-Meth­oxy­phen­yl)-1-pentyl-4,5-di­phenyl-1H-imidazole
title_fullStr 2-(4-Meth­oxy­phen­yl)-1-pentyl-4,5-di­phenyl-1H-imidazole
title_full_unstemmed 2-(4-Meth­oxy­phen­yl)-1-pentyl-4,5-di­phenyl-1H-imidazole
title_short 2-(4-Meth­oxy­phen­yl)-1-pentyl-4,5-di­phenyl-1H-imidazole
title_sort 2-(4-meth­oxy­phen­yl)-1-pentyl-4,5-di­phenyl-1h-imidazole
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588259/
https://www.ncbi.nlm.nih.gov/pubmed/23476433
http://dx.doi.org/10.1107/S1600536812049100
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