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Dibromido(2,9-dimethyl-1,10-phenanthroline-κ(2) N,N′)(dimethyl sulfoxide-κO)cadmium
In the molecule of the title compound, [CdBr(2)(C(14)H(12)N(2))(C(2)H(6)OS)], the Cd(II) atom is five-coordinated in a distorted trigonal–bipyramidal configuration by two N atoms from a 2,9-dimethyl-1,10-phenanthroline ligand, one O atom from a dimethyl sulfoxide ligand and two Br atoms. In the cry...
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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International Union of Crystallography
2012
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588265/ https://www.ncbi.nlm.nih.gov/pubmed/23476344 http://dx.doi.org/10.1107/S1600536812050106 |
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| author | Moghanlou, Khadijeh |
| author_facet | Moghanlou, Khadijeh |
| author_sort | Moghanlou, Khadijeh |
| collection | PubMed |
| description | In the molecule of the title compound, [CdBr(2)(C(14)H(12)N(2))(C(2)H(6)OS)], the Cd(II) atom is five-coordinated in a distorted trigonal–bipyramidal configuration by two N atoms from a 2,9-dimethyl-1,10-phenanthroline ligand, one O atom from a dimethyl sulfoxide ligand and two Br atoms. In the crystal, π–π contacts between the pyridine and benzene rings [centroid–centroid distances = 3.710 (5), 3.711 (6) and 3.627 (5) Å] stabilize the structure. |
| format | Online Article Text |
| id | pubmed-3588265 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2012 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-35882652013-03-08 Dibromido(2,9-dimethyl-1,10-phenanthroline-κ(2) N,N′)(dimethyl sulfoxide-κO)cadmium Moghanlou, Khadijeh Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the molecule of the title compound, [CdBr(2)(C(14)H(12)N(2))(C(2)H(6)OS)], the Cd(II) atom is five-coordinated in a distorted trigonal–bipyramidal configuration by two N atoms from a 2,9-dimethyl-1,10-phenanthroline ligand, one O atom from a dimethyl sulfoxide ligand and two Br atoms. In the crystal, π–π contacts between the pyridine and benzene rings [centroid–centroid distances = 3.710 (5), 3.711 (6) and 3.627 (5) Å] stabilize the structure. International Union of Crystallography 2012-12-12 /pmc/articles/PMC3588265/ /pubmed/23476344 http://dx.doi.org/10.1107/S1600536812050106 Text en © Khadijeh Moghanlou 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Moghanlou, Khadijeh Dibromido(2,9-dimethyl-1,10-phenanthroline-κ(2) N,N′)(dimethyl sulfoxide-κO)cadmium |
| title | Dibromido(2,9-dimethyl-1,10-phenanthroline-κ(2)
N,N′)(dimethyl sulfoxide-κO)cadmium |
| title_full | Dibromido(2,9-dimethyl-1,10-phenanthroline-κ(2)
N,N′)(dimethyl sulfoxide-κO)cadmium |
| title_fullStr | Dibromido(2,9-dimethyl-1,10-phenanthroline-κ(2)
N,N′)(dimethyl sulfoxide-κO)cadmium |
| title_full_unstemmed | Dibromido(2,9-dimethyl-1,10-phenanthroline-κ(2)
N,N′)(dimethyl sulfoxide-κO)cadmium |
| title_short | Dibromido(2,9-dimethyl-1,10-phenanthroline-κ(2)
N,N′)(dimethyl sulfoxide-κO)cadmium |
| title_sort | dibromido(2,9-dimethyl-1,10-phenanthroline-κ(2)
n,n′)(dimethyl sulfoxide-κo)cadmium |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588265/ https://www.ncbi.nlm.nih.gov/pubmed/23476344 http://dx.doi.org/10.1107/S1600536812050106 |
| work_keys_str_mv | AT moghanloukhadijeh dibromido29dimethyl110phenanthrolinek2nndimethylsulfoxidekocadmium |