catena-Poly[[tris­(acetonitrile-κN)praseodymium(III)]tris­(μ-trifluoro­methane­sulfonato-κ(2) O:O′)]

In the colourless title compound, [Pr(CF(3)O(3)S)(3)(CH(3)CN)(3)](n), the three trifluoro­methane­sulfonate anions form three bridges via O:O′-coordination between two Pr(III) atoms. The structure contains [Pr(NCMe)(3)-μ(2)(OTf)(3)—Pr(NCMe)(3)-μ(2)(OTf)(3)](n) (NCMe is acetonitrile; OTf is trifluoro...

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Detalles Bibliográficos
Autores principales: Apostolidis, Christos, Walter, Olaf
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588273/
https://www.ncbi.nlm.nih.gov/pubmed/23476322
http://dx.doi.org/10.1107/S1600536812049525
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author Apostolidis, Christos
Walter, Olaf
author_facet Apostolidis, Christos
Walter, Olaf
author_sort Apostolidis, Christos
collection PubMed
description In the colourless title compound, [Pr(CF(3)O(3)S)(3)(CH(3)CN)(3)](n), the three trifluoro­methane­sulfonate anions form three bridges via O:O′-coordination between two Pr(III) atoms. The structure contains [Pr(NCMe)(3)-μ(2)(OTf)(3)—Pr(NCMe)(3)-μ(2)(OTf)(3)](n) (NCMe is acetonitrile; OTf is trifluoromethanesulfonate) chains parallel to the a axis. The Pr(III) atom is nine-coordinate in a distorted tricapped trigonal-prismatic environment.
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spelling pubmed-35882732013-03-08 catena-Poly[[tris­(acetonitrile-κN)praseodymium(III)]tris­(μ-trifluoro­methane­sulfonato-κ(2) O:O′)] Apostolidis, Christos Walter, Olaf Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the colourless title compound, [Pr(CF(3)O(3)S)(3)(CH(3)CN)(3)](n), the three trifluoro­methane­sulfonate anions form three bridges via O:O′-coordination between two Pr(III) atoms. The structure contains [Pr(NCMe)(3)-μ(2)(OTf)(3)—Pr(NCMe)(3)-μ(2)(OTf)(3)](n) (NCMe is acetonitrile; OTf is trifluoromethanesulfonate) chains parallel to the a axis. The Pr(III) atom is nine-coordinate in a distorted tricapped trigonal-prismatic environment. International Union of Crystallography 2012-12-08 /pmc/articles/PMC3588273/ /pubmed/23476322 http://dx.doi.org/10.1107/S1600536812049525 Text en © Apostolidis and Walter 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Apostolidis, Christos
Walter, Olaf
catena-Poly[[tris­(acetonitrile-κN)praseodymium(III)]tris­(μ-trifluoro­methane­sulfonato-κ(2) O:O′)]
title catena-Poly[[tris­(acetonitrile-κN)praseodymium(III)]tris­(μ-trifluoro­methane­sulfonato-κ(2) O:O′)]
title_full catena-Poly[[tris­(acetonitrile-κN)praseodymium(III)]tris­(μ-trifluoro­methane­sulfonato-κ(2) O:O′)]
title_fullStr catena-Poly[[tris­(acetonitrile-κN)praseodymium(III)]tris­(μ-trifluoro­methane­sulfonato-κ(2) O:O′)]
title_full_unstemmed catena-Poly[[tris­(acetonitrile-κN)praseodymium(III)]tris­(μ-trifluoro­methane­sulfonato-κ(2) O:O′)]
title_short catena-Poly[[tris­(acetonitrile-κN)praseodymium(III)]tris­(μ-trifluoro­methane­sulfonato-κ(2) O:O′)]
title_sort catena-poly[[tris­(acetonitrile-κn)praseodymium(iii)]tris­(μ-trifluoro­methane­sulfonato-κ(2) o:o′)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588273/
https://www.ncbi.nlm.nih.gov/pubmed/23476322
http://dx.doi.org/10.1107/S1600536812049525
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