1,5-Dimethyl-2-phenyl-1H-pyrazol-3(2H)-one–4,4′-(propane-2,2-di­yl)bis­[1,5-dimethyl-2-phenyl-1H-pyrazol-3(2H)-one] (1/1)

The asymmetric unit of the title compound, C(11)H(12)N(2)O·C(25)H(28)N(4)O(2), contains two different mol­ecules. The smaller is known as anti­pyrine [systematic name: 1,5-dimethyl-2-phenyl-1H-pyrazol-3(2H)-one] and the larger is built up from two antypirine mol­ecules which are connected through a...

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Detalles Bibliográficos
Autor principal: Lyczko, Krzysztof
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588274/
https://www.ncbi.nlm.nih.gov/pubmed/23476388
http://dx.doi.org/10.1107/S160053681205091X
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author Lyczko, Krzysztof
author_facet Lyczko, Krzysztof
author_sort Lyczko, Krzysztof
collection PubMed
description The asymmetric unit of the title compound, C(11)H(12)N(2)O·C(25)H(28)N(4)O(2), contains two different mol­ecules. The smaller is known as anti­pyrine [systematic name: 1,5-dimethyl-2-phenyl-1H-pyrazol-3(2H)-one] and the larger is built up from two antypirine mol­ecules which are connected through a C atom of the pyrazolone ring to a central propanyl part [systematic name: 4,4′-(propane-2,2-di­yl)bis­[1,5-dimethyl-2-phenyl-1H-pyrazol-3(2H)-one]. Intra­molecular C—H⋯O hydrogen bonds occur in the latter mol­ecule. In the crystal, C—H⋯O hydrogen bonds link the mol­ecules into a two-dimensional network parallel to (001).
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spelling pubmed-35882742013-03-08 1,5-Dimethyl-2-phenyl-1H-pyrazol-3(2H)-one–4,4′-(propane-2,2-di­yl)bis­[1,5-dimethyl-2-phenyl-1H-pyrazol-3(2H)-one] (1/1) Lyczko, Krzysztof Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(11)H(12)N(2)O·C(25)H(28)N(4)O(2), contains two different mol­ecules. The smaller is known as anti­pyrine [systematic name: 1,5-dimethyl-2-phenyl-1H-pyrazol-3(2H)-one] and the larger is built up from two antypirine mol­ecules which are connected through a C atom of the pyrazolone ring to a central propanyl part [systematic name: 4,4′-(propane-2,2-di­yl)bis­[1,5-dimethyl-2-phenyl-1H-pyrazol-3(2H)-one]. Intra­molecular C—H⋯O hydrogen bonds occur in the latter mol­ecule. In the crystal, C—H⋯O hydrogen bonds link the mol­ecules into a two-dimensional network parallel to (001). International Union of Crystallography 2012-12-22 /pmc/articles/PMC3588274/ /pubmed/23476388 http://dx.doi.org/10.1107/S160053681205091X Text en © Krzysztof Lyczko 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Lyczko, Krzysztof
1,5-Dimethyl-2-phenyl-1H-pyrazol-3(2H)-one–4,4′-(propane-2,2-di­yl)bis­[1,5-dimethyl-2-phenyl-1H-pyrazol-3(2H)-one] (1/1)
title 1,5-Dimethyl-2-phenyl-1H-pyrazol-3(2H)-one–4,4′-(propane-2,2-di­yl)bis­[1,5-dimethyl-2-phenyl-1H-pyrazol-3(2H)-one] (1/1)
title_full 1,5-Dimethyl-2-phenyl-1H-pyrazol-3(2H)-one–4,4′-(propane-2,2-di­yl)bis­[1,5-dimethyl-2-phenyl-1H-pyrazol-3(2H)-one] (1/1)
title_fullStr 1,5-Dimethyl-2-phenyl-1H-pyrazol-3(2H)-one–4,4′-(propane-2,2-di­yl)bis­[1,5-dimethyl-2-phenyl-1H-pyrazol-3(2H)-one] (1/1)
title_full_unstemmed 1,5-Dimethyl-2-phenyl-1H-pyrazol-3(2H)-one–4,4′-(propane-2,2-di­yl)bis­[1,5-dimethyl-2-phenyl-1H-pyrazol-3(2H)-one] (1/1)
title_short 1,5-Dimethyl-2-phenyl-1H-pyrazol-3(2H)-one–4,4′-(propane-2,2-di­yl)bis­[1,5-dimethyl-2-phenyl-1H-pyrazol-3(2H)-one] (1/1)
title_sort 1,5-dimethyl-2-phenyl-1h-pyrazol-3(2h)-one–4,4′-(propane-2,2-di­yl)bis­[1,5-dimethyl-2-phenyl-1h-pyrazol-3(2h)-one] (1/1)
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588274/
https://www.ncbi.nlm.nih.gov/pubmed/23476388
http://dx.doi.org/10.1107/S160053681205091X
work_keys_str_mv AT lyczkokrzysztof 15dimethyl2phenyl1hpyrazol32hone44propane22diylbis15dimethyl2phenyl1hpyrazol32hone11

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