β-K(VO(2))(2)(PO(4))

A new vanadium oxide, potassium bis­(dioxovanad­yl) phosphate, β-K(VO(2))(2)(PO(4)), has been synthesized by a solid-state reaction. In the title compound, the [V(2)PO(8)] framework is built up from infinite pyramidal [V(2)O(8)](∞) and [VPO(7)](∞) chains linked together by V—O—P bridges, leading to...

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Detalles Bibliográficos
Autores principales: Ezzine Yahmed, Safa, Ayed, Meriem, Zid, Mohamed Faouzi, Driss, Ahmed
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Inorganic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588275/
https://www.ncbi.nlm.nih.gov/pubmed/23476311
http://dx.doi.org/10.1107/S1600536812049884
Descripción
Sumario:A new vanadium oxide, potassium bis­(dioxovanad­yl) phosphate, β-K(VO(2))(2)(PO(4)), has been synthesized by a solid-state reaction. In the title compound, the [V(2)PO(8)] framework is built up from infinite pyramidal [V(2)O(8)](∞) and [VPO(7)](∞) chains linked together by V—O—P bridges, leading to a three-dimensional framework which delimits two types of inter­secting tunnels running along [100] and [010] in which the four unique K(+) ions, showing coordination numbers of nine and ten, are located.

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