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β-K(VO(2))(2)(PO(4))
A new vanadium oxide, potassium bis(dioxovanadyl) phosphate, β-K(VO(2))(2)(PO(4)), has been synthesized by a solid-state reaction. In the title compound, the [V(2)PO(8)] framework is built up from infinite pyramidal [V(2)O(8)](∞) and [VPO(7)](∞) chains linked together by V—O—P bridges, leading to...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588275/ https://www.ncbi.nlm.nih.gov/pubmed/23476311 http://dx.doi.org/10.1107/S1600536812049884 |
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author | Ezzine Yahmed, Safa Ayed, Meriem Zid, Mohamed Faouzi Driss, Ahmed |
author_facet | Ezzine Yahmed, Safa Ayed, Meriem Zid, Mohamed Faouzi Driss, Ahmed |
author_sort | Ezzine Yahmed, Safa |
collection | PubMed |
description | A new vanadium oxide, potassium bis(dioxovanadyl) phosphate, β-K(VO(2))(2)(PO(4)), has been synthesized by a solid-state reaction. In the title compound, the [V(2)PO(8)] framework is built up from infinite pyramidal [V(2)O(8)](∞) and [VPO(7)](∞) chains linked together by V—O—P bridges, leading to a three-dimensional framework which delimits two types of intersecting tunnels running along [100] and [010] in which the four unique K(+) ions, showing coordination numbers of nine and ten, are located. |
format | Online Article Text |
id | pubmed-3588275 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-35882752013-03-08 β-K(VO(2))(2)(PO(4)) Ezzine Yahmed, Safa Ayed, Meriem Zid, Mohamed Faouzi Driss, Ahmed Acta Crystallogr Sect E Struct Rep Online Inorganic Papers A new vanadium oxide, potassium bis(dioxovanadyl) phosphate, β-K(VO(2))(2)(PO(4)), has been synthesized by a solid-state reaction. In the title compound, the [V(2)PO(8)] framework is built up from infinite pyramidal [V(2)O(8)](∞) and [VPO(7)](∞) chains linked together by V—O—P bridges, leading to a three-dimensional framework which delimits two types of intersecting tunnels running along [100] and [010] in which the four unique K(+) ions, showing coordination numbers of nine and ten, are located. International Union of Crystallography 2012-12-12 /pmc/articles/PMC3588275/ /pubmed/23476311 http://dx.doi.org/10.1107/S1600536812049884 Text en © Ezzine Yahmed et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Inorganic Papers Ezzine Yahmed, Safa Ayed, Meriem Zid, Mohamed Faouzi Driss, Ahmed β-K(VO(2))(2)(PO(4)) |
title | β-K(VO(2))(2)(PO(4)) |
title_full | β-K(VO(2))(2)(PO(4)) |
title_fullStr | β-K(VO(2))(2)(PO(4)) |
title_full_unstemmed | β-K(VO(2))(2)(PO(4)) |
title_short | β-K(VO(2))(2)(PO(4)) |
title_sort | β-k(vo(2))(2)(po(4)) |
topic | Inorganic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588275/ https://www.ncbi.nlm.nih.gov/pubmed/23476311 http://dx.doi.org/10.1107/S1600536812049884 |
work_keys_str_mv | AT ezzineyahmedsafa bkvo22po4 AT ayedmeriem bkvo22po4 AT zidmohamedfaouzi bkvo22po4 AT drissahmed bkvo22po4 |