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Aqua­(4-cyano­pyridine-κN (4))(5,10,15,20-tetra­phenyl­porphyrinato-κ(4) N)magnesium

In the title complex, [Mg(C(44)H(28)N(4))(C(6)H(4)N(2))(H(2)O)], the Mg(2+) cation is octa­hedrally coordinated and lies on an inversion center with the axially located 4-cyano­pyridine and aqua ligands exhibiting 50% substitutional disorder. The cyano-bound 4-cyano­pyridine mol­ecule also is disord...

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Autores principales: Ezzayani, Khaireddine, Belkhiria, Mohamed Salah, Najmudin, Shabir, Bonifácio, Cecilia, Nasri, Habib
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588276/
https://www.ncbi.nlm.nih.gov/pubmed/23476319
http://dx.doi.org/10.1107/S1600536812049434
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author Ezzayani, Khaireddine
Belkhiria, Mohamed Salah
Najmudin, Shabir
Bonifácio, Cecilia
Nasri, Habib
author_facet Ezzayani, Khaireddine
Belkhiria, Mohamed Salah
Najmudin, Shabir
Bonifácio, Cecilia
Nasri, Habib
author_sort Ezzayani, Khaireddine
collection PubMed
description In the title complex, [Mg(C(44)H(28)N(4))(C(6)H(4)N(2))(H(2)O)], the Mg(2+) cation is octa­hedrally coordinated and lies on an inversion center with the axially located 4-cyano­pyridine and aqua ligands exhibiting 50% substitutional disorder. The cyano-bound 4-cyano­pyridine mol­ecule also is disordered across the inversion centre. The four N atoms of the pyrrole rings of the dianionic 5,10,15,20-tetra­phenyl­porphyrin ligand occupy the equatorial sites of the octa­hedron [Mg—N = 2.0552 (10) and 2.0678 (11) Å] and the axial Mg—(N,O) bond length is 2.3798 (12) Å. The crystal packing is stabilized by weak inter­molecular C—H⋯π inter­actions.
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spelling pubmed-35882762013-03-08 Aqua­(4-cyano­pyridine-κN (4))(5,10,15,20-tetra­phenyl­porphyrinato-κ(4) N)magnesium Ezzayani, Khaireddine Belkhiria, Mohamed Salah Najmudin, Shabir Bonifácio, Cecilia Nasri, Habib Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Mg(C(44)H(28)N(4))(C(6)H(4)N(2))(H(2)O)], the Mg(2+) cation is octa­hedrally coordinated and lies on an inversion center with the axially located 4-cyano­pyridine and aqua ligands exhibiting 50% substitutional disorder. The cyano-bound 4-cyano­pyridine mol­ecule also is disordered across the inversion centre. The four N atoms of the pyrrole rings of the dianionic 5,10,15,20-tetra­phenyl­porphyrin ligand occupy the equatorial sites of the octa­hedron [Mg—N = 2.0552 (10) and 2.0678 (11) Å] and the axial Mg—(N,O) bond length is 2.3798 (12) Å. The crystal packing is stabilized by weak inter­molecular C—H⋯π inter­actions. International Union of Crystallography 2012-12-08 /pmc/articles/PMC3588276/ /pubmed/23476319 http://dx.doi.org/10.1107/S1600536812049434 Text en © Ezzayani et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ezzayani, Khaireddine
Belkhiria, Mohamed Salah
Najmudin, Shabir
Bonifácio, Cecilia
Nasri, Habib
Aqua­(4-cyano­pyridine-κN (4))(5,10,15,20-tetra­phenyl­porphyrinato-κ(4) N)magnesium
title Aqua­(4-cyano­pyridine-κN (4))(5,10,15,20-tetra­phenyl­porphyrinato-κ(4) N)magnesium
title_full Aqua­(4-cyano­pyridine-κN (4))(5,10,15,20-tetra­phenyl­porphyrinato-κ(4) N)magnesium
title_fullStr Aqua­(4-cyano­pyridine-κN (4))(5,10,15,20-tetra­phenyl­porphyrinato-κ(4) N)magnesium
title_full_unstemmed Aqua­(4-cyano­pyridine-κN (4))(5,10,15,20-tetra­phenyl­porphyrinato-κ(4) N)magnesium
title_short Aqua­(4-cyano­pyridine-κN (4))(5,10,15,20-tetra­phenyl­porphyrinato-κ(4) N)magnesium
title_sort aqua­(4-cyano­pyridine-κn (4))(5,10,15,20-tetra­phenyl­porphyrinato-κ(4) n)magnesium
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588276/
https://www.ncbi.nlm.nih.gov/pubmed/23476319
http://dx.doi.org/10.1107/S1600536812049434
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