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Aqua(4-cyanopyridine-κN (4))(5,10,15,20-tetraphenylporphyrinato-κ(4) N)magnesium
In the title complex, [Mg(C(44)H(28)N(4))(C(6)H(4)N(2))(H(2)O)], the Mg(2+) cation is octahedrally coordinated and lies on an inversion center with the axially located 4-cyanopyridine and aqua ligands exhibiting 50% substitutional disorder. The cyano-bound 4-cyanopyridine molecule also is disord...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588276/ https://www.ncbi.nlm.nih.gov/pubmed/23476319 http://dx.doi.org/10.1107/S1600536812049434 |
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author | Ezzayani, Khaireddine Belkhiria, Mohamed Salah Najmudin, Shabir Bonifácio, Cecilia Nasri, Habib |
author_facet | Ezzayani, Khaireddine Belkhiria, Mohamed Salah Najmudin, Shabir Bonifácio, Cecilia Nasri, Habib |
author_sort | Ezzayani, Khaireddine |
collection | PubMed |
description | In the title complex, [Mg(C(44)H(28)N(4))(C(6)H(4)N(2))(H(2)O)], the Mg(2+) cation is octahedrally coordinated and lies on an inversion center with the axially located 4-cyanopyridine and aqua ligands exhibiting 50% substitutional disorder. The cyano-bound 4-cyanopyridine molecule also is disordered across the inversion centre. The four N atoms of the pyrrole rings of the dianionic 5,10,15,20-tetraphenylporphyrin ligand occupy the equatorial sites of the octahedron [Mg—N = 2.0552 (10) and 2.0678 (11) Å] and the axial Mg—(N,O) bond length is 2.3798 (12) Å. The crystal packing is stabilized by weak intermolecular C—H⋯π interactions. |
format | Online Article Text |
id | pubmed-3588276 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-35882762013-03-08 Aqua(4-cyanopyridine-κN (4))(5,10,15,20-tetraphenylporphyrinato-κ(4) N)magnesium Ezzayani, Khaireddine Belkhiria, Mohamed Salah Najmudin, Shabir Bonifácio, Cecilia Nasri, Habib Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Mg(C(44)H(28)N(4))(C(6)H(4)N(2))(H(2)O)], the Mg(2+) cation is octahedrally coordinated and lies on an inversion center with the axially located 4-cyanopyridine and aqua ligands exhibiting 50% substitutional disorder. The cyano-bound 4-cyanopyridine molecule also is disordered across the inversion centre. The four N atoms of the pyrrole rings of the dianionic 5,10,15,20-tetraphenylporphyrin ligand occupy the equatorial sites of the octahedron [Mg—N = 2.0552 (10) and 2.0678 (11) Å] and the axial Mg—(N,O) bond length is 2.3798 (12) Å. The crystal packing is stabilized by weak intermolecular C—H⋯π interactions. International Union of Crystallography 2012-12-08 /pmc/articles/PMC3588276/ /pubmed/23476319 http://dx.doi.org/10.1107/S1600536812049434 Text en © Ezzayani et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Ezzayani, Khaireddine Belkhiria, Mohamed Salah Najmudin, Shabir Bonifácio, Cecilia Nasri, Habib Aqua(4-cyanopyridine-κN (4))(5,10,15,20-tetraphenylporphyrinato-κ(4) N)magnesium |
title | Aqua(4-cyanopyridine-κN
(4))(5,10,15,20-tetraphenylporphyrinato-κ(4)
N)magnesium |
title_full | Aqua(4-cyanopyridine-κN
(4))(5,10,15,20-tetraphenylporphyrinato-κ(4)
N)magnesium |
title_fullStr | Aqua(4-cyanopyridine-κN
(4))(5,10,15,20-tetraphenylporphyrinato-κ(4)
N)magnesium |
title_full_unstemmed | Aqua(4-cyanopyridine-κN
(4))(5,10,15,20-tetraphenylporphyrinato-κ(4)
N)magnesium |
title_short | Aqua(4-cyanopyridine-κN
(4))(5,10,15,20-tetraphenylporphyrinato-κ(4)
N)magnesium |
title_sort | aqua(4-cyanopyridine-κn
(4))(5,10,15,20-tetraphenylporphyrinato-κ(4)
n)magnesium |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588276/ https://www.ncbi.nlm.nih.gov/pubmed/23476319 http://dx.doi.org/10.1107/S1600536812049434 |
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