Diaqua­bis­[4-(1H-imidazol-2-yl)pyridine-κN]bis­(nitrato-κO)cadmium

In the title compound, [Cd(NO(3))(2)(C(8)H(7)N(3))(2)(H(2)O)(2)], the Cd(II) cation is situated on an inversion center and is coordinated by the O atoms of two nitrate anions, by the N atoms of two 4-(imidazol-2-yl)pyridine ligands and by two water O atoms in a slightly distorted N(2)O(4) octa­hedra...

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Detalles Bibliográficos
Autores principales: Zhang, Chuan-Yue, Wang, Tao, Jin, Chuan-Ming
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588280/
https://www.ncbi.nlm.nih.gov/pubmed/23476357
http://dx.doi.org/10.1107/S1600536812050908
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author Zhang, Chuan-Yue
Wang, Tao
Jin, Chuan-Ming
author_facet Zhang, Chuan-Yue
Wang, Tao
Jin, Chuan-Ming
author_sort Zhang, Chuan-Yue
collection PubMed
description In the title compound, [Cd(NO(3))(2)(C(8)H(7)N(3))(2)(H(2)O)(2)], the Cd(II) cation is situated on an inversion center and is coordinated by the O atoms of two nitrate anions, by the N atoms of two 4-(imidazol-2-yl)pyridine ligands and by two water O atoms in a slightly distorted N(2)O(4) octa­hedral geometry. The dihedral angle between the imidazole and pyridine rings is 1.6 (2)°. In the crystal, mol­ecules are linked by N—H⋯O, O—H⋯N and O—H⋯O hydrogen bonds, forming a three-dimensional network.
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spelling pubmed-35882802013-03-08 Diaqua­bis­[4-(1H-imidazol-2-yl)pyridine-κN]bis­(nitrato-κO)cadmium Zhang, Chuan-Yue Wang, Tao Jin, Chuan-Ming Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cd(NO(3))(2)(C(8)H(7)N(3))(2)(H(2)O)(2)], the Cd(II) cation is situated on an inversion center and is coordinated by the O atoms of two nitrate anions, by the N atoms of two 4-(imidazol-2-yl)pyridine ligands and by two water O atoms in a slightly distorted N(2)O(4) octa­hedral geometry. The dihedral angle between the imidazole and pyridine rings is 1.6 (2)°. In the crystal, mol­ecules are linked by N—H⋯O, O—H⋯N and O—H⋯O hydrogen bonds, forming a three-dimensional network. International Union of Crystallography 2012-12-22 /pmc/articles/PMC3588280/ /pubmed/23476357 http://dx.doi.org/10.1107/S1600536812050908 Text en © Zhang et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhang, Chuan-Yue
Wang, Tao
Jin, Chuan-Ming
Diaqua­bis­[4-(1H-imidazol-2-yl)pyridine-κN]bis­(nitrato-κO)cadmium
title Diaqua­bis­[4-(1H-imidazol-2-yl)pyridine-κN]bis­(nitrato-κO)cadmium
title_full Diaqua­bis­[4-(1H-imidazol-2-yl)pyridine-κN]bis­(nitrato-κO)cadmium
title_fullStr Diaqua­bis­[4-(1H-imidazol-2-yl)pyridine-κN]bis­(nitrato-κO)cadmium
title_full_unstemmed Diaqua­bis­[4-(1H-imidazol-2-yl)pyridine-κN]bis­(nitrato-κO)cadmium
title_short Diaqua­bis­[4-(1H-imidazol-2-yl)pyridine-κN]bis­(nitrato-κO)cadmium
title_sort diaqua­bis­[4-(1h-imidazol-2-yl)pyridine-κn]bis­(nitrato-κo)cadmium
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588280/
https://www.ncbi.nlm.nih.gov/pubmed/23476357
http://dx.doi.org/10.1107/S1600536812050908
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