Anilinium-3-carboxyl­ate 3-carb­oxy­anilinium nitrate

The title compound, C(7)H(8)NO(2) (+)·NO(3) (−)·C(7)H(7)NO(2), exists in the form of a protonated dimer of two anilinium-3-carboxyl­ate mol­ecules related by an inversion center, and a nitrate anion located on a twofold rotation axis. The bridging H atom occupies, with equal probability, the two sit...

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Autores principales: Ahmad, Saeed, Hussain, Sajjad, Sharif, Shahzad, Khan, Islam Ullah, Tahir, Muhammad Nawaz
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588283/
https://www.ncbi.nlm.nih.gov/pubmed/23476416
http://dx.doi.org/10.1107/S1600536812049392
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author Ahmad, Saeed
Hussain, Sajjad
Sharif, Shahzad
Khan, Islam Ullah
Tahir, Muhammad Nawaz
author_facet Ahmad, Saeed
Hussain, Sajjad
Sharif, Shahzad
Khan, Islam Ullah
Tahir, Muhammad Nawaz
author_sort Ahmad, Saeed
collection PubMed
description The title compound, C(7)H(8)NO(2) (+)·NO(3) (−)·C(7)H(7)NO(2), exists in the form of a protonated dimer of two anilinium-3-carboxyl­ate mol­ecules related by an inversion center, and a nitrate anion located on a twofold rotation axis. The bridging H atom occupies, with equal probability, the two sites associated with the carboxyl atoms. In addition to the strong O—H⋯O hydrogen bond, in the crystal, the various units are linked via N—H⋯O and C—H⋯O hydrogen bonds forming a three-dimensional structure.
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spelling pubmed-35882832013-03-08 Anilinium-3-carboxyl­ate 3-carb­oxy­anilinium nitrate Ahmad, Saeed Hussain, Sajjad Sharif, Shahzad Khan, Islam Ullah Tahir, Muhammad Nawaz Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(7)H(8)NO(2) (+)·NO(3) (−)·C(7)H(7)NO(2), exists in the form of a protonated dimer of two anilinium-3-carboxyl­ate mol­ecules related by an inversion center, and a nitrate anion located on a twofold rotation axis. The bridging H atom occupies, with equal probability, the two sites associated with the carboxyl atoms. In addition to the strong O—H⋯O hydrogen bond, in the crystal, the various units are linked via N—H⋯O and C—H⋯O hydrogen bonds forming a three-dimensional structure. International Union of Crystallography 2012-12-08 /pmc/articles/PMC3588283/ /pubmed/23476416 http://dx.doi.org/10.1107/S1600536812049392 Text en © Ahmad et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Ahmad, Saeed
Hussain, Sajjad
Sharif, Shahzad
Khan, Islam Ullah
Tahir, Muhammad Nawaz
Anilinium-3-carboxyl­ate 3-carb­oxy­anilinium nitrate
title Anilinium-3-carboxyl­ate 3-carb­oxy­anilinium nitrate
title_full Anilinium-3-carboxyl­ate 3-carb­oxy­anilinium nitrate
title_fullStr Anilinium-3-carboxyl­ate 3-carb­oxy­anilinium nitrate
title_full_unstemmed Anilinium-3-carboxyl­ate 3-carb­oxy­anilinium nitrate
title_short Anilinium-3-carboxyl­ate 3-carb­oxy­anilinium nitrate
title_sort anilinium-3-carboxyl­ate 3-carb­oxy­anilinium nitrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588283/
https://www.ncbi.nlm.nih.gov/pubmed/23476416
http://dx.doi.org/10.1107/S1600536812049392
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