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Carbon­yl{3,3′-di-tert-butyl-5,5′-dimeth­oxy-2,2′-bis­[(4,4,5,5-tetra­methyl-1,3,2-dioxaphospho­lan-2-yl)­oxy]biphenyl-κ(2) P,P′}hydrido(triphenyl­phosphane-κP)rhodium(I) diethyl ether tris­olvate

In the title compound, [RhH(C(74)H(68)O(8)P(2))(C(18)H(15)P)(CO)]·3C(4)H(10)O, the CHP(3) coordination set at the Rh(I) ion is arranged in a distorted trigonal–bipyramidal geometry with the P atoms adopting equatorial coordination sites and the C atom of the carbonyl ligand as well as the H atom ado...

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Detalles Bibliográficos
Autores principales: Selent, Detlef, Spannenberg, Anke, Börner, Armin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588287/
https://www.ncbi.nlm.nih.gov/pubmed/23476316
http://dx.doi.org/10.1107/S1600536812049124
Descripción
Sumario:In the title compound, [RhH(C(74)H(68)O(8)P(2))(C(18)H(15)P)(CO)]·3C(4)H(10)O, the CHP(3) coordination set at the Rh(I) ion is arranged in a distorted trigonal–bipyramidal geometry with the P atoms adopting equatorial coordination sites and the C atom of the carbonyl ligand as well as the H atom adopting the axial sites. The asymmetric unit contains two very similar mol­ecules of the rhodium complex, two half-occupied diethyl ether mol­ecules and further diethyl ether solvent mol­ecules which could not be modelled successfully. Therefore contributions of the latter were removed from the diffraction data using the SQUEEZE procedure in PLATON [Spek (2009 ▶). Acta Cryst. D65, 148–155].