Carbon­yl{3,3′-di-tert-butyl-5,5′-dimeth­oxy-2,2′-bis­[(4,4,5,5-tetra­methyl-1,3,2-dioxaphospho­lan-2-yl)­oxy]biphenyl-κ(2) P,P′}hydrido(triphenyl­phosphane-κP)rhodium(I) diethyl ether tris­olvate

In the title compound, [RhH(C(74)H(68)O(8)P(2))(C(18)H(15)P)(CO)]·3C(4)H(10)O, the CHP(3) coordination set at the Rh(I) ion is arranged in a distorted trigonal–bipyramidal geometry with the P atoms adopting equatorial coordination sites and the C atom of the carbonyl ligand as well as the H atom ado...

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Detalles Bibliográficos
Autores principales: Selent, Detlef, Spannenberg, Anke, Börner, Armin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588287/
https://www.ncbi.nlm.nih.gov/pubmed/23476316
http://dx.doi.org/10.1107/S1600536812049124
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author Selent, Detlef
Spannenberg, Anke
Börner, Armin
author_facet Selent, Detlef
Spannenberg, Anke
Börner, Armin
author_sort Selent, Detlef
collection PubMed
description In the title compound, [RhH(C(74)H(68)O(8)P(2))(C(18)H(15)P)(CO)]·3C(4)H(10)O, the CHP(3) coordination set at the Rh(I) ion is arranged in a distorted trigonal–bipyramidal geometry with the P atoms adopting equatorial coordination sites and the C atom of the carbonyl ligand as well as the H atom adopting the axial sites. The asymmetric unit contains two very similar mol­ecules of the rhodium complex, two half-occupied diethyl ether mol­ecules and further diethyl ether solvent mol­ecules which could not be modelled successfully. Therefore contributions of the latter were removed from the diffraction data using the SQUEEZE procedure in PLATON [Spek (2009 ▶). Acta Cryst. D65, 148–155].
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spelling pubmed-35882872013-03-08 Carbon­yl{3,3′-di-tert-butyl-5,5′-dimeth­oxy-2,2′-bis­[(4,4,5,5-tetra­methyl-1,3,2-dioxaphospho­lan-2-yl)­oxy]biphenyl-κ(2) P,P′}hydrido(triphenyl­phosphane-κP)rhodium(I) diethyl ether tris­olvate Selent, Detlef Spannenberg, Anke Börner, Armin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [RhH(C(74)H(68)O(8)P(2))(C(18)H(15)P)(CO)]·3C(4)H(10)O, the CHP(3) coordination set at the Rh(I) ion is arranged in a distorted trigonal–bipyramidal geometry with the P atoms adopting equatorial coordination sites and the C atom of the carbonyl ligand as well as the H atom adopting the axial sites. The asymmetric unit contains two very similar mol­ecules of the rhodium complex, two half-occupied diethyl ether mol­ecules and further diethyl ether solvent mol­ecules which could not be modelled successfully. Therefore contributions of the latter were removed from the diffraction data using the SQUEEZE procedure in PLATON [Spek (2009 ▶). Acta Cryst. D65, 148–155]. International Union of Crystallography 2012-12-05 /pmc/articles/PMC3588287/ /pubmed/23476316 http://dx.doi.org/10.1107/S1600536812049124 Text en © Selent et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Selent, Detlef
Spannenberg, Anke
Börner, Armin
Carbon­yl{3,3′-di-tert-butyl-5,5′-dimeth­oxy-2,2′-bis­[(4,4,5,5-tetra­methyl-1,3,2-dioxaphospho­lan-2-yl)­oxy]biphenyl-κ(2) P,P′}hydrido(triphenyl­phosphane-κP)rhodium(I) diethyl ether tris­olvate
title Carbon­yl{3,3′-di-tert-butyl-5,5′-dimeth­oxy-2,2′-bis­[(4,4,5,5-tetra­methyl-1,3,2-dioxaphospho­lan-2-yl)­oxy]biphenyl-κ(2) P,P′}hydrido(triphenyl­phosphane-κP)rhodium(I) diethyl ether tris­olvate
title_full Carbon­yl{3,3′-di-tert-butyl-5,5′-dimeth­oxy-2,2′-bis­[(4,4,5,5-tetra­methyl-1,3,2-dioxaphospho­lan-2-yl)­oxy]biphenyl-κ(2) P,P′}hydrido(triphenyl­phosphane-κP)rhodium(I) diethyl ether tris­olvate
title_fullStr Carbon­yl{3,3′-di-tert-butyl-5,5′-dimeth­oxy-2,2′-bis­[(4,4,5,5-tetra­methyl-1,3,2-dioxaphospho­lan-2-yl)­oxy]biphenyl-κ(2) P,P′}hydrido(triphenyl­phosphane-κP)rhodium(I) diethyl ether tris­olvate
title_full_unstemmed Carbon­yl{3,3′-di-tert-butyl-5,5′-dimeth­oxy-2,2′-bis­[(4,4,5,5-tetra­methyl-1,3,2-dioxaphospho­lan-2-yl)­oxy]biphenyl-κ(2) P,P′}hydrido(triphenyl­phosphane-κP)rhodium(I) diethyl ether tris­olvate
title_short Carbon­yl{3,3′-di-tert-butyl-5,5′-dimeth­oxy-2,2′-bis­[(4,4,5,5-tetra­methyl-1,3,2-dioxaphospho­lan-2-yl)­oxy]biphenyl-κ(2) P,P′}hydrido(triphenyl­phosphane-κP)rhodium(I) diethyl ether tris­olvate
title_sort carbon­yl{3,3′-di-tert-butyl-5,5′-dimeth­oxy-2,2′-bis­[(4,4,5,5-tetra­methyl-1,3,2-dioxaphospho­lan-2-yl)­oxy]biphenyl-κ(2) p,p′}hydrido(triphenyl­phosphane-κp)rhodium(i) diethyl ether tris­olvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588287/
https://www.ncbi.nlm.nih.gov/pubmed/23476316
http://dx.doi.org/10.1107/S1600536812049124
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